Izvorni znanstveni članak
https://doi.org/10.17113/ftb.53.04.15.4176
Sensitive Voltammetric Determination of Natural Flavonoid Quercetin on a Disposable Graphite Lead
Dai Long Vu
; University of Pardubice, Studentska 573, CZ-53210 Pardubice, Czech Republic
Simona Žabčíková
; University of Pardubice, Studentska 573, CZ-53210 Pardubice, Czech Republic
Libor Červenka
; University of Pardubice, Studentska 573, CZ-53210 Pardubice, Czech Republic
Bensu Ertek
; Canakkale Onsekiz Mart University, Mart University 18, TR-17100 Canakkale, Turkey
Yusuf Dilgin
; Canakkale Onsekiz Mart University, Mart University 18, TR-17100 Canakkale, Turkey
Sažetak
In this paper, a pencil graphite electrode was pretreated using chronoamperometry technique in phosphate buffer solution (pH=7.0) for sensitive determination of quercetin. Oxidation of quercetin was investigated using pretreated pencil graphite electrode and anodic stripping differential pulse voltammetry. Under optimal conditions, the anodic current of quercetin exhibited linear response to its concentration in the range from 0.001 to 1.5 μmol/L with the limit of detection of 0.3·10–3 μmol/L. The proposed method was successfully applied for the determination of quercetin in cranberry and blackcurrant juices with recovery rate from 93.2 to 94.7 %. Solid-phase extraction was found to be necessary prior to voltammetric determination of quercetin in fruit juice samples using pretreated pencil graphite electrode.
Ključne riječi
pencil graphite electrode; voltammetry; quercetin; fruit juices
Hrčak ID:
150128
URI
Datum izdavanja:
28.12.2015.
Posjeta: 1.380 *