Croatica Chemica Acta, Vol. 89 No. 1, 2016.
Izvorni znanstveni članak
https://doi.org/10.5562/cca2820
Investigation of Synthesis and some Properties of the Copper Complexes Containing Imidazole Ligand
Emin Erdem
; Department of Chemistry, Faculty of Science&Arts, Pamukkale University, 20017, Denizli-Turkey
Mehri Akarsu
; Department of Chemistry, Faculty of Science&Arts, Pamukkale University, 20017, Denizli-Turkey
Rafet Kılınçarslan
; Department of Chemistry, Faculty of Science&Arts, Pamukkale University, 20017, Denizli-Turkey
İsmail Kayağil
; Department of Chemistry, Faculty of Science&Arts M. Akif Ersoy University, 15030, Burdur-Turkey
İzzet Kara
; Department of Science Education, Pamukkale University, 20070, Denizli-Turkey
Sevil Söyleyici
; Department of Chemistry, Faculty of Science&Arts, Pamukkale University, 20017, Denizli-Turkey
Sažetak
The copper(II) complexes bearing tetrasubstituted imidazole derivatives containing oxygen donor as ligands (L1-6) were synthesized and characterized by spectroscopic methods, magnetic measurements, elemental and thermogravimetric analyses. The fluorescence efficiency of the ligands (L1-6) and their copper(II) complexes were investigated at r.t. in DMF solution. Theoretical calculations were performed for the copper(II) complex of L4 ligand, in this study. The molecular geometry, bond lengths, bond angles and vibrational wave numbers were calculated by using ab initio calculations based on the Hartree-Fock{HF/6-31G(d)} and the density functional theory {B3LYP/6-31G(d)} in the ground state.
This work is licensed under a Creative Commons Attribution 4.0 International License.
Ključne riječi
copper(II); fluorescence; tetrasubstituted imidazole; Hartree-Fock
Hrčak ID:
158796
URI
Datum izdavanja:
20.6.2016.
Posjeta: 2.981 *