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Original scientific paper

π-Facial Selectivity in Diels-Alder Cycloadditions

Alan P. Marchand ; Department of Chemistry, University of North Texas, Denton, Texas 76203-5070, USA
Hyun-Soon Chong ; Department of Chemistry, University of North Texas, Denton, Texas 76203-5070, USA
Bishwajit Ganguly ; Department of Chemistry, University of North Texas, Denton, Texas 76203-5070, USA
James M. Coxon ; Department of Chemistry, University of Canterbury, Christchurch, New Zealand

Fulltext: english, pdf (141 KB) pages 1027-1038 downloads: 275* cite
APA 6th Edition
Marchand, A.P., Chong, H., Ganguly, B. & Coxon, J.M. (2000). π-Facial Selectivity in Diels-Alder Cycloadditions. Croatica Chemica Acta, 73 (4), 1027-1038. Retrieved from https://hrcak.srce.hr/131985
MLA 8th Edition
Marchand, Alan P., et al. "π-Facial Selectivity in Diels-Alder Cycloadditions." Croatica Chemica Acta, vol. 73, no. 4, 2000, pp. 1027-1038. https://hrcak.srce.hr/131985. Accessed 23 Sep. 2021.
Chicago 17th Edition
Marchand, Alan P., Hyun-Soon Chong, Bishwajit Ganguly and James M. Coxon. "π-Facial Selectivity in Diels-Alder Cycloadditions." Croatica Chemica Acta 73, no. 4 (2000): 1027-1038. https://hrcak.srce.hr/131985
Harvard
Marchand, A.P., et al. (2000). 'π-Facial Selectivity in Diels-Alder Cycloadditions', Croatica Chemica Acta, 73(4), pp. 1027-1038. Available at: https://hrcak.srce.hr/131985 (Accessed 23 September 2021)
Vancouver
Marchand AP, Chong H, Ganguly B, Coxon JM. π-Facial Selectivity in Diels-Alder Cycloadditions. Croatica Chemica Acta [Internet]. 2000 [cited 2021 September 23];73(4):1027-1038. Available from: https://hrcak.srce.hr/131985
IEEE
A.P. Marchand, H. Chong, B. Ganguly and J.M. Coxon, "π-Facial Selectivity in Diels-Alder Cycloadditions", Croatica Chemica Acta, vol.73, no. 4, pp. 1027-1038, 2000. [Online]. Available: https://hrcak.srce.hr/131985. [Accessed: 23 September 2021]

Abstracts
Diels-Alder reactions between π-facially differentiated dienes and/or π-facially differentiated dienophiles frequently proceed with remark-able π-facial selectivity. Experimental and theoretical studies have been undertaken in an effort to gain insight into the fundamental origins of this phenomenon. Reactions of interest in this connection include thermal [4 + 2] cycloadditions between (i) various dienophiles and cage-annulated 1,3-cyclohexadienes (i.e. systems 1, 4, 6, and 9) and (ii) various dienes and cage-annulated dienophiles (i.e. systems 1a, 11a, and 14). The results of relevant molecular mechanics, semiempirical, and ab initio molecular orbital calculations generally are consistent with experiment.

Keywords
π -facial selectivity; Diels-Alder cycloadditions

Hrčak ID: 131985

URI
https://hrcak.srce.hr/131985

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