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A Formal Pro of of Vessel-Shape Dependency of the Ideal-Gas One-Particle Partition Function of Translation

Zdenek Slanina ; Department of Chemistry, Faculty of Science, Hokkaida University, Sapporo 060, Japan


Puni tekst: engleski pdf 2.086 Kb

str. 769-772

preuzimanja: 187

citiraj


Sažetak

An erroneous limiting behaviour of the conventional translational partition function q has been pointed out. Some general features of the exact translational partition function Q are given. A formal proof that Q (from a rigorous point of view) depends on the shape of vessel is presented. A possible relation of the result to experimental observations is briefly discussed.

Ključne riječi

Hrčak ID:

177304

URI

https://hrcak.srce.hr/177304

Datum izdavanja:

25.7.1986.

Posjeta: 500 *