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https://doi.org/10.5599/jese.409

Simulation of square wave voltammetry of three electrode reactions coupled by two reversible chemical reactions

Milivoj Lovrić orcid id orcid.org/0000-0002-6421-1398 ; Divkovićeva 13, Zagreb 10090, Croatia


Puni tekst: engleski pdf 933 Kb

str. 119-129

preuzimanja: 369

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Sažetak

Three fast and reversible electrode reactions that are connected by two reversible chemical reactions that are permanently in the equilibrium are analysed theoretically for square wave voltammetry. The dependence of peak potentials on the dimensionless equilibrium constants of chemical reactions is calculated. The influence of the basic thermodynamic parameters on the square wave voltammetric responses is analysed.

Ključne riječi

ECECE mechanism; equilibrium conditions; voltammetry; theory

Hrčak ID:

185731

URI

https://hrcak.srce.hr/185731

Datum izdavanja:

15.8.2017.

Posjeta: 825 *