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The Electrophile Desolvation Process in Nucleophile-Electrophile Combination Reactions

Juan Bertran ; Departmento de Quimica Fisica, Universidad de Sevilla., Sevilla, Spain
Julio Anguiano ; Departmento de Quimica Fisica, Universidad de Sevilla., Sevilla, Spain
Antonio Oliva ; Departamento de Quimica Fisica. Universidad Autonoma de Barcelona. Bellaterra. Spain.

Sažetak

The protonation and methylation of ethylene in different
solvents are studied, by means of the MIND0/3 method, in order
to check the hypothesis of partial desolvation of the electrophile
at the transition state. It has been found that the degree of
desolvation depends on both the electrophile and the solvent. The
consequences of these results are discussed.

Ključne riječi

Hrčak ID:

194221

URI

https://hrcak.srce.hr/194221

Datum izdavanja:

30.6.1983.

Posjeta: 659 *