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Original scientific paper

Gas Phase Structure of Sodiated Amino Acids Probed by H/D Exchange Reactions

Marko Rožman

Fulltext: english, pdf (86 KB) pages 185-188 downloads: 735* cite
APA 6th Edition
Rožman, M. (2005). Gas Phase Structure of Sodiated Amino Acids Probed by H/D Exchange Reactions. Croatica Chemica Acta, 78 (2), 185-188. Retrieved from https://hrcak.srce.hr/10
MLA 8th Edition
Rožman, Marko. "Gas Phase Structure of Sodiated Amino Acids Probed by H/D Exchange Reactions." Croatica Chemica Acta, vol. 78, no. 2, 2005, pp. 185-188. https://hrcak.srce.hr/10. Accessed 26 Sep. 2021.
Chicago 17th Edition
Rožman, Marko. "Gas Phase Structure of Sodiated Amino Acids Probed by H/D Exchange Reactions." Croatica Chemica Acta 78, no. 2 (2005): 185-188. https://hrcak.srce.hr/10
Harvard
Rožman, M. (2005). 'Gas Phase Structure of Sodiated Amino Acids Probed by H/D Exchange Reactions', Croatica Chemica Acta, 78(2), pp. 185-188. Available at: https://hrcak.srce.hr/10 (Accessed 26 September 2021)
Vancouver
Rožman M. Gas Phase Structure of Sodiated Amino Acids Probed by H/D Exchange Reactions. Croatica Chemica Acta [Internet]. 2005 [cited 2021 September 26];78(2):185-188. Available from: https://hrcak.srce.hr/10
IEEE
M. Rožman, "Gas Phase Structure of Sodiated Amino Acids Probed by H/D Exchange Reactions", Croatica Chemica Acta, vol.78, no. 2, pp. 185-188, 2005. [Online]. Available: https://hrcak.srce.hr/10. [Accessed: 26 September 2021]

Abstracts
Taking into account the difference in structure of a sodiated gas phase amino acid in its zwitterionic and charge solvated forms, gas phase structures of sodiated histidine, lysine, phenylalanine, proline, tryptophan and tyrosine were probed by H/D exchange reactions. Experiment results obtained from the site-specific reaction rate constants indicated the zwitterionic structure for all the sodiated amino acids studied. In contrast, B3LYP calculations for sodiated lysine, along with the already presented theoretical results for other amino acids studied, show the charge solvated form to be stable, except for proline which is in the zwitterionic form. Absence of H/D exchange in sodiated methyl esters of phenylalanine and histidine, along with the discrepancy between experimental and theoretical data for the amino acids studied, indicates that H/D exchange occurs only when sodiated amino acids are in the zwitterionic form.

Keywords
gas phase structure sodium cationized amino acids sodium cationized amino acid esters mass spectrometry density functional theory zwitterionic structure

Hrčak ID: 10

URI
https://hrcak.srce.hr/10

[croatian]

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