hrcak mascot   Srce   HID

Izvorni znanstveni članak
https://doi.org/10.5562/cca1714

Photothermal Reactions of Nitrosobenzene and Halonitrosobenzenes in Solid-state

Anamarija Knežević ; Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102A, 10000 Zagreb, Croatia
Tina Medančić ; Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102A, 10000 Zagreb, Croatia
Srđan Milovac ; Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102A, 10000 Zagreb, Croatia
Ivana Biljan ; Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102A, 10000 Zagreb, Croatia
Ivan Halasz ; Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102A, 10000 Zagreb, Croatia
Hrvoj Vančik   ORCID icon orcid.org/0000-0002-4218-9214 ; Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102A, 10000 Zagreb, Croatia

Puni tekst: engleski, pdf (3 MB) str. 21-24 preuzimanja: 893* citiraj
APA 6th Edition
Knežević, A., Medančić, T., Milovac, S., Biljan, I., Halasz, I. i Vančik, H. (2011). Photothermal Reactions of Nitrosobenzene and Halonitrosobenzenes in Solid-state. Croatica Chemica Acta, 84 (1), 21-24. https://doi.org/10.5562/cca1714
MLA 8th Edition
Knežević, Anamarija, et al. "Photothermal Reactions of Nitrosobenzene and Halonitrosobenzenes in Solid-state." Croatica Chemica Acta, vol. 84, br. 1, 2011, str. 21-24. https://doi.org/10.5562/cca1714. Citirano 16.11.2019.
Chicago 17th Edition
Knežević, Anamarija, Tina Medančić, Srđan Milovac, Ivana Biljan, Ivan Halasz i Hrvoj Vančik. "Photothermal Reactions of Nitrosobenzene and Halonitrosobenzenes in Solid-state." Croatica Chemica Acta 84, br. 1 (2011): 21-24. https://doi.org/10.5562/cca1714
Harvard
Knežević, A., et al. (2011). 'Photothermal Reactions of Nitrosobenzene and Halonitrosobenzenes in Solid-state', Croatica Chemica Acta, 84(1), str. 21-24. https://doi.org/10.5562/cca1714
Vancouver
Knežević A, Medančić T, Milovac S, Biljan I, Halasz I, Vančik H. Photothermal Reactions of Nitrosobenzene and Halonitrosobenzenes in Solid-state. Croatica Chemica Acta [Internet]. 2011 [pristupljeno 16.11.2019.];84(1):21-24. https://doi.org/10.5562/cca1714
IEEE
A. Knežević, T. Medančić, S. Milovac, I. Biljan, I. Halasz i H. Vančik, "Photothermal Reactions of Nitrosobenzene and Halonitrosobenzenes in Solid-state", Croatica Chemica Acta, vol.84, br. 1, str. 21-24, 2011. [Online]. https://doi.org/10.5562/cca1714

Sažetak
Photothermal reactions of the dimers of nitrosobenzene, m-chloronitrosobenzene, and p-chloronitrosobenzene were studied in solid-state by IR spectroscopy at low temperatures and by X-ray powder diffraction. It was found for the first time that photothermal cycle (photolytic dissociation fol-lowed by thermal dimerization) could successively be performed also with Z-configured dimeric nitroso-benzene. Halonitrosobenzenes dimers with E-configuration afforded different photo behavior depending on the po-sition of halogen atom on the benzene ring: while m-halonitrosobenzenes do not dissociate under UV ir-radiation, p-chloronitrosobenzene, as well as previously studied p-bromonitrosobenzene photolyses very efficiently with recovering of the original crystal phase. Kinetics of thermal dimerization was measured in solid-state, and it was found that the reaction phase transformation occurs as a two-dimensional growth through the crystal. (doi: 10.5562/cca1714)

Ključne riječi
nitrosobenzenes; photothermal reactions; solid-state

Hrčak ID: 69690

URI
https://hrcak.srce.hr/69690

Posjeta: 1.285 *