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Croatica Chemica Acta, Vol. 84 No. 4, 2011.

Izvorni znanstveni članak
https://doi.org/10.5562/cca1855

Synthesis of (1-ethyl-2-phenyl-1,4-dihydroquinolin-4-yl)-(2,4,6-trimethylphenyl)-amine by Electrochemical Methods in Aprotic Media

Mamta Kumari ; Department of Chemistry, University of Rajasthan, Jaipur 302055, India
Digish Kumar Sharma ; Department of Chemistry, University of Rajasthan, Jaipur 302055, India

Puni tekst: engleski, pdf (2 MB) str. 455-460 preuzimanja: 1.331* citiraj
APA 6th Edition
Kumari, M. i Sharma, D.K. (2011). Synthesis of (1-ethyl-2-phenyl-1,4-dihydroquinolin-4-yl)-(2,4,6-trimethylphenyl)-amine by Electrochemical Methods in Aprotic Media. Croatica Chemica Acta, 84 (4), 455-460. https://doi.org/10.5562/cca1855
MLA 8th Edition
Kumari, Mamta i Digish Kumar Sharma. "Synthesis of (1-ethyl-2-phenyl-1,4-dihydroquinolin-4-yl)-(2,4,6-trimethylphenyl)-amine by Electrochemical Methods in Aprotic Media." Croatica Chemica Acta, vol. 84, br. 4, 2011, str. 455-460. https://doi.org/10.5562/cca1855. Citirano 08.03.2021.
Chicago 17th Edition
Kumari, Mamta i Digish Kumar Sharma. "Synthesis of (1-ethyl-2-phenyl-1,4-dihydroquinolin-4-yl)-(2,4,6-trimethylphenyl)-amine by Electrochemical Methods in Aprotic Media." Croatica Chemica Acta 84, br. 4 (2011): 455-460. https://doi.org/10.5562/cca1855
Harvard
Kumari, M., i Sharma, D.K. (2011). 'Synthesis of (1-ethyl-2-phenyl-1,4-dihydroquinolin-4-yl)-(2,4,6-trimethylphenyl)-amine by Electrochemical Methods in Aprotic Media', Croatica Chemica Acta, 84(4), str. 455-460. https://doi.org/10.5562/cca1855
Vancouver
Kumari M, Sharma DK. Synthesis of (1-ethyl-2-phenyl-1,4-dihydroquinolin-4-yl)-(2,4,6-trimethylphenyl)-amine by Electrochemical Methods in Aprotic Media. Croatica Chemica Acta [Internet]. 2011 [pristupljeno 08.03.2021.];84(4):455-460. https://doi.org/10.5562/cca1855
IEEE
M. Kumari i D.K. Sharma, "Synthesis of (1-ethyl-2-phenyl-1,4-dihydroquinolin-4-yl)-(2,4,6-trimethylphenyl)-amine by Electrochemical Methods in Aprotic Media", Croatica Chemica Acta, vol.84, br. 4, str. 455-460, 2011. [Online]. https://doi.org/10.5562/cca1855

Sažetak
The formation of (1-ethyl-2-phenyl-1,4-dihydroquinolin-4-yl)-(2,4,6-trimethylphenyl)-amine by
the electro reduction of (1-ethyl-2-phenyl-1H-quinolin-4-ylidene)-(2,4,6-trimethylphenyl)-amine occurs
through acceptance of two electrons accompanied by two successive peaks, each electron peak followed
by a chemical reaction. The electrochemical reduction of (1-ethyl-2-phenyl-1H-quinolin-4-ylidene)-
(2,4,6-trimethyl-phenyl)-amine was investigated in 0.1 M tetrabutylammoniumbromide in N,N-dimethylformamide
at glassy carbon electrode using the technique of cyclic voltammetry at the room temperature
(290K). In this medium the first peak was observed at –0.831 V (vs. Ag|Ag+) at the glassy carbon electrode
(GCE) surface, which is more stable and well defined as compared to the second peak. The diffusion
coefficient (D) of investigated imine in the investigated solvent media has been calculated using the modified
Randles-Sevcik equation. The electron transfer coefficient (α) of the reactant species has also been
calculated. (doi: 10.5562/cca1855)

Ključne riječi
electroreduction; cyclic voltammetry; glassy carbon electrode (GCE); diffusion coefficient (D)

Hrčak ID: 75049

URI
https://hrcak.srce.hr/75049

Posjeta: 1.737 *