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Croatica Chemica Acta, Vol.77 No.1-2 Svibanj 2004.

Izvorni znanstveni članak

Isotope Effect in the Gas Phase Reaction of Pyrene-d10 with Nb+ Ions

Saša Kazazić ; Laboratory for Chemical Kinetics and Atmospheric Chemistry, Rugjer Bošković Institute, HR-10002 Zagreb, Croatia
Leo Klasinc ; Laboratory for Chemical Kinetics and Atmospheric Chemistry, Rugjer Bošković Institute, HR-10002 Zagreb, Croatia
Marko Rožman ; Laboratory for Chemical Kinetics and Atmospheric Chemistry, Rugjer Bošković Institute, HR-10002 Zagreb, Croatia
Dunja Srzić ; Laboratory for Chemical Kinetics and Atmospheric Chemistry, Rugjer Bošković Institute, HR-10002 Zagreb, Croatia
Jan von Knop ; Rechenzentrum der Universität Düsseldorf, D-2 Düsseldorf, Germany

Puni tekst: engleski, pdf (73 KB) str. 321-324 preuzimanja: 177* citiraj
APA 6th Edition
Kazazić, S., Klasinc, L., Rožman, M., Srzić, D. i von Knop, J. (2004). Isotope Effect in the Gas Phase Reaction of Pyrene-d10 with Nb+ Ions. Croatica Chemica Acta, 77 (1-2), 321-324. Preuzeto s https://hrcak.srce.hr/102723
MLA 8th Edition
Kazazić, Saša, et al. "Isotope Effect in the Gas Phase Reaction of Pyrene-d10 with Nb+ Ions." Croatica Chemica Acta, vol. 77, br. 1-2, 2004, str. 321-324. https://hrcak.srce.hr/102723. Citirano 18.06.2018.
Chicago 17th Edition
Kazazić, Saša, Leo Klasinc, Marko Rožman, Dunja Srzić i Jan von Knop. "Isotope Effect in the Gas Phase Reaction of Pyrene-d10 with Nb+ Ions." Croatica Chemica Acta 77, br. 1-2 (2004): 321-324. https://hrcak.srce.hr/102723

Sažetak
The deuterium isotope effect in the gas phase ligation of niobium (Nb) monocations by a mixture of pyrene and perdeutero pyrene was studied in a FTMS instrument. The attachment of pyrene (pyrene-d10) is followed by a rapid release of hydrogen (deuterium) from the Nb-pyrene (Nb-pyrene-d10) cation, respectively. The dehydrogenated product formation depends on the experimental conditions in the reaction chamber. A 1,2-elimination of H2 (D2) from the ligation product is proposed.

Ključne riječi
gas phase reaction; Fourier transform mass spectrometry; deuterium kinetic isotope effect; niobium (II); pyrene; pyrene-d10

Hrčak ID: 102723

URI
https://hrcak.srce.hr/102723

Posjeta: 264 *