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Original scientific paper

A Model of CE Mechanism on Spherical Electrodes

Milivoj Lovrić ; Center for Marine and Environmental Research, Ruđer Bošković Institute, P.O. Box 180, Zagreb 10002, Croatia
Yakov I. Tur'yan ; The National Physical Laboratory of Israel, Danciger »A« Bldg, Givat Ram, 91904 Jerusalem, Israel

Fulltext: english, pdf (128 KB) pages 189-197 downloads: 318* cite
APA 6th Edition
Lovrić, M. & Tur'yan, Y.I. (2003). A Model of CE Mechanism on Spherical Electrodes. Croatica Chemica Acta, 76 (3), 189-197. Retrieved from https://hrcak.srce.hr/103168
MLA 8th Edition
Lovrić, Milivoj and Yakov I. Tur'yan. "A Model of CE Mechanism on Spherical Electrodes." Croatica Chemica Acta, vol. 76, no. 3, 2003, pp. 189-197. https://hrcak.srce.hr/103168. Accessed 13 Apr. 2021.
Chicago 17th Edition
Lovrić, Milivoj and Yakov I. Tur'yan. "A Model of CE Mechanism on Spherical Electrodes." Croatica Chemica Acta 76, no. 3 (2003): 189-197. https://hrcak.srce.hr/103168
Harvard
Lovrić, M., and Tur'yan, Y.I. (2003). 'A Model of CE Mechanism on Spherical Electrodes', Croatica Chemica Acta, 76(3), pp. 189-197. Available at: https://hrcak.srce.hr/103168 (Accessed 13 April 2021)
Vancouver
Lovrić M, Tur'yan YI. A Model of CE Mechanism on Spherical Electrodes. Croatica Chemica Acta [Internet]. 2003 [cited 2021 April 13];76(3):189-197. Available from: https://hrcak.srce.hr/103168
IEEE
M. Lovrić and Y.I. Tur'yan, "A Model of CE Mechanism on Spherical Electrodes", Croatica Chemica Acta, vol.76, no. 3, pp. 189-197, 2003. [Online]. Available: https://hrcak.srce.hr/103168. [Accessed: 13 April 2021]

Abstracts
A model of electrode reaction preceded by a first-order chemical reaction under chronoamperometric conditions on spherical electrodes has been developed. A general solution applying to all values of equilibrium constants, including very small ones, was obtained by numerical integration. Well-known analytical solutions for steady-state and near-steady-state conditions and for pure kinetic currents were shown to be special cases of the general solution. The conditions for their application are given.

Keywords
CE mechanism; chronoamperometry; spherical electrodes; microelectrodes

Hrčak ID: 103168

URI
https://hrcak.srce.hr/103168

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