hrcak mascot   Srce   HID

Original scientific paper

Synthesis of Two Molybdenum(VI) Complexes Coordinated by Schiff Base Derivatives: N-Phenyl-2-hidroxy-1-naphthaldimine and N-Benzyl-2-hidroxy-1-naphthaldimine. Molecular and Crystal Structure of [MoO2(C5H7O2)(OCH3)(2-OC10H6CH=NHC6H5)]

Marina Cindrić   ORCID icon orcid.org/0000-0003-3062-9902 ; Chemistry Department, Faculty of Science, University of Zagreb, Ul. kralja Zvonimira 8, 10000 Zagreb, Croatia
Neven Strukan ; Chemistry Department, Faculty of Science, University of Zagreb, Ul. kralja Zvonimira 8, 10000 Zagreb, Croatia
Višnja Vrdoljak ; Chemistry Department, Faculty of Science, University of Zagreb, Ul. kralja Zvonimira 8, 10000 Zagreb, Croatia
Tanja Kajfež ; Chemistry Department, Faculty of Science, University of Zagreb, Ul. kralja Zvonimira 8, 10000 Zagreb, Croatia
Boris Kamenar ; Chemistry Department, Faculty of Science, University of Zagreb, Ul. kralja Zvonimira 8, 10000 Zagreb, Croatia

Fulltext: english, pdf (169 KB) pages 257-261 downloads: 892* cite
APA 6th Edition
Cindrić, M., Strukan, N., Vrdoljak, V., Kajfež, T. & Kamenar, B. (2003). Synthesis of Two Molybdenum(VI) Complexes Coordinated by Schiff Base Derivatives: N-Phenyl-2-hidroxy-1-naphthaldimine and N-Benzyl-2-hidroxy-1-naphthaldimine. Molecular and Crystal Structure of [MoO2(C5H7O2)(OCH3)(2-OC10H6CH=NHC6H5)]. Croatica Chemica Acta, 76 (3), 257-261. Retrieved from https://hrcak.srce.hr/103176
MLA 8th Edition
Cindrić, Marina, et al. "Synthesis of Two Molybdenum(VI) Complexes Coordinated by Schiff Base Derivatives: N-Phenyl-2-hidroxy-1-naphthaldimine and N-Benzyl-2-hidroxy-1-naphthaldimine. Molecular and Crystal Structure of [MoO2(C5H7O2)(OCH3)(2-OC10H6CH=NHC6H5)]." Croatica Chemica Acta, vol. 76, no. 3, 2003, pp. 257-261. https://hrcak.srce.hr/103176. Accessed 14 Apr. 2021.
Chicago 17th Edition
Cindrić, Marina, Neven Strukan, Višnja Vrdoljak, Tanja Kajfež and Boris Kamenar. "Synthesis of Two Molybdenum(VI) Complexes Coordinated by Schiff Base Derivatives: N-Phenyl-2-hidroxy-1-naphthaldimine and N-Benzyl-2-hidroxy-1-naphthaldimine. Molecular and Crystal Structure of [MoO2(C5H7O2)(OCH3)(2-OC10H6CH=NHC6H5)]." Croatica Chemica Acta 76, no. 3 (2003): 257-261. https://hrcak.srce.hr/103176
Harvard
Cindrić, M., et al. (2003). 'Synthesis of Two Molybdenum(VI) Complexes Coordinated by Schiff Base Derivatives: N-Phenyl-2-hidroxy-1-naphthaldimine and N-Benzyl-2-hidroxy-1-naphthaldimine. Molecular and Crystal Structure of [MoO2(C5H7O2)(OCH3)(2-OC10H6CH=NHC6H5)]', Croatica Chemica Acta, 76(3), pp. 257-261. Available at: https://hrcak.srce.hr/103176 (Accessed 14 April 2021)
Vancouver
Cindrić M, Strukan N, Vrdoljak V, Kajfež T, Kamenar B. Synthesis of Two Molybdenum(VI) Complexes Coordinated by Schiff Base Derivatives: N-Phenyl-2-hidroxy-1-naphthaldimine and N-Benzyl-2-hidroxy-1-naphthaldimine. Molecular and Crystal Structure of [MoO2(C5H7O2)(OCH3)(2-OC10H6CH=NHC6H5)]. Croatica Chemica Acta [Internet]. 2003 [cited 2021 April 14];76(3):257-261. Available from: https://hrcak.srce.hr/103176
IEEE
M. Cindrić, N. Strukan, V. Vrdoljak, T. Kajfež and B. Kamenar, "Synthesis of Two Molybdenum(VI) Complexes Coordinated by Schiff Base Derivatives: N-Phenyl-2-hidroxy-1-naphthaldimine and N-Benzyl-2-hidroxy-1-naphthaldimine. Molecular and Crystal Structure of [MoO2(C5H7O2)(OCH3)(2-OC10H6CH=NHC6H5)]", Croatica Chemica Acta, vol.76, no. 3, pp. 257-261, 2003. [Online]. Available: https://hrcak.srce.hr/103176. [Accessed: 14 April 2021]

Abstracts
The synthesis of two monomeric molybdenum(VI) Schiff base complexes derived from N-phenyl-2-hidroxy-1-naphthaldimine and N-benzyl-2-hidroxy-1-naphthaldimine: [MoO2(C5H7O2)(OCH3)(2-OC10H6CH=NHC6H5)] (I) and [MoO2(C5H7O2)(OCH3)(2-OC10H6CH=NHCH2C6H5)] (II) described in this paper are the first examples in which potentially bidentate Schiff bases are monodentately bonded to molybdenum as zwitterionic ligands. The structure of complex I was determined by X-ray analysis. Within the same ligand, the hydrogen atom attached to nitrogen forms an intramolecular hydrogen bond of 2.548(2) Å with the oxygen atom coordinated to molybdenum. The octahedral coordination of molybdenum is completed by two oxo-oxygens, two acetylacetonato oxygens and one methoxy oxygen. The compounds were characterized by chemical analysis, IR spectroscopy and single crystal structure determination.

Keywords
molybdenum(VI); Schiff bases; complexes; crystal structure

Hrčak ID: 103176

URI
https://hrcak.srce.hr/103176

Visits: 1.089 *