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Biocatalytic reductions by plant tissue - Green alternative to alcohol production

Dajana Gašo-Sokač ; Josip Juraj Strossmayer University of Osijek, Faculty of Food Technology Osijek, Franje Kuhaca 20, HR-31000 Osijek, Croatia
Marija Nujić ; Josip Juraj Strossmayer University of Osijek, Faculty of Food Technology Osijek, Franje Kuhaca 20, HR-31000 Osijek, Croatia
Valentina Bušić ; Josip Juraj Strossmayer University of Osijek, Faculty of Food Technology Osijek, Franje Kuhaca 20, HR-31000 Osijek, Croatia
Mirna Habuda-Stanić ; Josip Juraj Strossmayer University of Osijek, Faculty of Food Technology Osijek, Franje Kuhaca 20, HR-31000 Osijek, Croatia

Puni tekst: engleski, pdf (459 KB) str. 51-60 preuzimanja: 1.554* citiraj
APA 6th Edition
Gašo-Sokač, D., Nujić, M., Bušić, V. i Habuda-Stanić, M. (2014). Biocatalytic reductions by plant tissue - Green alternative to alcohol production. Croatian journal of food science and technology, 6 (1), 51-60. Preuzeto s https://hrcak.srce.hr/125421
MLA 8th Edition
Gašo-Sokač, Dajana, et al. "Biocatalytic reductions by plant tissue - Green alternative to alcohol production." Croatian journal of food science and technology, vol. 6, br. 1, 2014, str. 51-60. https://hrcak.srce.hr/125421. Citirano 22.09.2019.
Chicago 17th Edition
Gašo-Sokač, Dajana, Marija Nujić, Valentina Bušić i Mirna Habuda-Stanić. "Biocatalytic reductions by plant tissue - Green alternative to alcohol production." Croatian journal of food science and technology 6, br. 1 (2014): 51-60. https://hrcak.srce.hr/125421
Harvard
Gašo-Sokač, D., et al. (2014). 'Biocatalytic reductions by plant tissue - Green alternative to alcohol production', Croatian journal of food science and technology, 6(1), str. 51-60. Preuzeto s: https://hrcak.srce.hr/125421 (Datum pristupa: 22.09.2019.)
Vancouver
Gašo-Sokač D, Nujić M, Bušić V, Habuda-Stanić M. Biocatalytic reductions by plant tissue - Green alternative to alcohol production. Croatian journal of food science and technology [Internet]. 2014 [pristupljeno 22.09.2019.];6(1):51-60. Dostupno na: https://hrcak.srce.hr/125421
IEEE
D. Gašo-Sokač, M. Nujić, V. Bušić i M. Habuda-Stanić, "Biocatalytic reductions by plant tissue - Green alternative to alcohol production", Croatian journal of food science and technology, vol.6, br. 1, str. 51-60, 2014. [Online]. Dostupno na: https://hrcak.srce.hr/125421. [Citirano: 22.09.2019.]

Sažetak
The use of biocatalysts for the industrial synthesis of chemicals has been attracting much attention as an environmental friendly synthetic method. Various plants, such as apple (Malus pumila), carrot (Daucus carota), cucumber (Cucumis sativus), onion (Allium cepa), potato (Solanum tuberosum), radish (Raphanus sativus) and sweet potato (Ipomoea batatas) were used as biocatalysts. Enzymes that plants produce are able to perform reactions under mild conditions (pH and temperature), with remarkable chemo-, regio-, and stereoselectivity. Due to this feature the number of biocatalysts used in organic synthesis has rapidly increased during the last decades, especially for the production of chiral compounds. This review presents biotechnological processes for the production of chiral alcohols by reducing prochiral ketones with whole plant tissue. Chiral alcohols are important building blocks for the synthesis of pharmaceuticals, pesticides, pheromones, flavors, fragrances and advanced materials such as liquid crystals. Reductase-catalyzed reactions are dependent on cofactors, and therefore, one major task in process development is to provide an effective method for regeneration of the cofactors consumed. The need for expensive cofactors is eliminated by using the whole plant tissue since the plant automatically provides this requirement. Depending on the vegetable used, either enantiomer may be obtained in high yield and high enantiomeric excess (ee), which could be a critical factor for drug development/bioactivity evaluation perspective. In this paper, various processes carried out on laboratory scales are presented. Attention is turned to conversion, yield, enantiomeric excess (ee).

Ključne riječi
biocatalysts; ketone reduction; plant tissue

Hrčak ID: 125421

URI
https://hrcak.srce.hr/125421

Posjeta: 1.767 *