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https://doi.org/10.5562/cca2289

Supramolecular Interactions Involved in the Solid State Structure of N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine

Arab K. El-Qisairi   ORCID icon orcid.org/0000-0001-9745-9253 ; Department of Chemistry, Faculty of Science, Mu’tah University, Mu’tah 61710, Jordan
Hanan A. Qaseer ; Department of Chemistry, Faculty of Science, Mu’tah University, Mu’tah 61710, Jordan
Solhe F. Alshahateet ; Department of Chemistry, Faculty of Science, Mu’tah University, Mu’tah 61710, Jordan
M. K. Hasan Qaseer ; Department of Physics, Faculty of Science, Jordan University of Science and Technology, P.O.Box 3030, Irbid, Jordan
Mukarram H. Zaghal ; Department of Chemistry, Faculty of Science, Yarmouk University, Irbid, Jordan
Wa'el Al-Btoush ; Department of Chemistry, Faculty of Science, Mu’tah University, Mu’tah 61710, Jordan
Louise N. Dawe ; Centre for Chemical Analysis, Research and Training, Memorial University of Newfoundland St. John’s, NL, A1B 3X7, Canada

Puni tekst: engleski, pdf (4 MB) str. 123-128 preuzimanja: 628* citiraj
APA 6th Edition
El-Qisairi, A.K., Qaseer, H.A., Alshahateet, S.F., Qaseer, M.K.H., Zaghal, M.H., Al-Btoush, W. i Dawe, L.N. (2014). Supramolecular Interactions Involved in the Solid State Structure of N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine. Croatica Chemica Acta, 87 (2), 123-128. https://doi.org/10.5562/cca2289
MLA 8th Edition
El-Qisairi, Arab K., et al. "Supramolecular Interactions Involved in the Solid State Structure of N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine." Croatica Chemica Acta, vol. 87, br. 2, 2014, str. 123-128. https://doi.org/10.5562/cca2289. Citirano 28.02.2021.
Chicago 17th Edition
El-Qisairi, Arab K., Hanan A. Qaseer, Solhe F. Alshahateet, M. K. Hasan Qaseer, Mukarram H. Zaghal, Wa'el Al-Btoush i Louise N. Dawe. "Supramolecular Interactions Involved in the Solid State Structure of N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine." Croatica Chemica Acta 87, br. 2 (2014): 123-128. https://doi.org/10.5562/cca2289
Harvard
El-Qisairi, A.K., et al. (2014). 'Supramolecular Interactions Involved in the Solid State Structure of N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine', Croatica Chemica Acta, 87(2), str. 123-128. https://doi.org/10.5562/cca2289
Vancouver
El-Qisairi AK, Qaseer HA, Alshahateet SF, Qaseer MKH, Zaghal MH, Al-Btoush W i sur. Supramolecular Interactions Involved in the Solid State Structure of N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine. Croatica Chemica Acta [Internet]. 2014 [pristupljeno 28.02.2021.];87(2):123-128. https://doi.org/10.5562/cca2289
IEEE
A.K. El-Qisairi, et al., "Supramolecular Interactions Involved in the Solid State Structure of N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine", Croatica Chemica Acta, vol.87, br. 2, str. 123-128, 2014. [Online]. https://doi.org/10.5562/cca2289

Sažetak
The structure of the symmetrical Schiff base, N,N'-[bis(pyridin-2-yl)formylidene]ethane-1,2-diamine (bpfd) has been characterized by single crystal X-ray diffraction. The non-covalent supramolecular chemistry involved in the crystal structure of this ligand has been carefully investigated. The structure adopted different motifs of nitrogen-hydrogen interactions that led to the formation of centrosymmetric dimers. In addition, edge-edge and face-face nitrogen-nitrogen interactions were ob-served and reported. The Schiff base (bpfd) ligand crystallizes in a monoclinic space group C12/c1 with a = 19.128(2) Å; b = 5.8776(6) Å; c = 13.1403(15) Å; α = 90o; β = 121.970o(4); γ = 90o and z = 4. This structure is an example of compounds with many symmetry-independent molecules in the asymmetric unit cell (Z > 2).

Ključne riječi
centrosymmetric dimer interactions; unit cell packing arrangement; spectral properties; high Z-value structure

Hrčak ID: 126965

URI
https://hrcak.srce.hr/126965

Posjeta: 908 *