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https://doi.org/10.5562/cca2454

Photochemical Approach to New Polycyclic Substrates Suitable for Further Photocatalytic Functionalization

Dragana Vuk ; Department of Organic Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, 10000 Zagreb, Croatia
Željko Marinić   ORCID icon orcid.org/0000-0002-7459-1451 ; Center for NMR, Rudjer Bošković Institute, Bijenička cesta 54, 10000 Zagreb, Croatia
Irena Škorić   ORCID icon orcid.org/0000-0002-1563-7261 ; Department of Organic Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, 10000 Zagreb, Croatia

Puni tekst: engleski, pdf (2 MB) str. 465-473 preuzimanja: 329* citiraj
APA 6th Edition
Vuk, D., Marinić, Ž. i Škorić, I. (2014). Photochemical Approach to New Polycyclic Substrates Suitable for Further Photocatalytic Functionalization. Croatica Chemica Acta, 87 (4), 465-473. https://doi.org/10.5562/cca2454
MLA 8th Edition
Vuk, Dragana, et al. "Photochemical Approach to New Polycyclic Substrates Suitable for Further Photocatalytic Functionalization." Croatica Chemica Acta, vol. 87, br. 4, 2014, str. 465-473. https://doi.org/10.5562/cca2454. Citirano 19.07.2019.
Chicago 17th Edition
Vuk, Dragana, Željko Marinić i Irena Škorić. "Photochemical Approach to New Polycyclic Substrates Suitable for Further Photocatalytic Functionalization." Croatica Chemica Acta 87, br. 4 (2014): 465-473. https://doi.org/10.5562/cca2454
Harvard
Vuk, D., Marinić, Ž., i Škorić, I. (2014). 'Photochemical Approach to New Polycyclic Substrates Suitable for Further Photocatalytic Functionalization', Croatica Chemica Acta, 87(4), str. 465-473. https://doi.org/10.5562/cca2454
Vancouver
Vuk D, Marinić Ž, Škorić I. Photochemical Approach to New Polycyclic Substrates Suitable for Further Photocatalytic Functionalization. Croatica Chemica Acta [Internet]. 2014 [pristupljeno 19.07.2019.];87(4):465-473. https://doi.org/10.5562/cca2454
IEEE
D. Vuk, Ž. Marinić i I. Škorić, "Photochemical Approach to New Polycyclic Substrates Suitable for Further Photocatalytic Functionalization", Croatica Chemica Acta, vol.87, br. 4, str. 465-473, 2014. [Online]. https://doi.org/10.5562/cca2454

Sažetak
New polycyclic compounds are synthesized by photocycloaddition reactions of methoxy, methyl or phenyl substituted butadiene derivatives 11−14. Mono- and dimethoxy butadiene derivatives 11 and 12 undergo intramolecular [2+2] photocycloaddition giving benzobicyclo[3.2.1]octadiene structures (endo-15, endo,trans-17) as main products. As minor photoproducts tricyclic compounds endo-16 and endo,trans-18 are isolated, respectively, formed by [4+2] photoinduced cycloaddition of the starting molecules. The reaction of compounds 13 and 14 is more selective and only benzobicy-clo[3.2.1]octadienes endo,endo-19 and endo,endo-20 are formed, respectively. New bicy-clo[3.2.1]octadienes with isolated double bond can be suitable substrates for further efficient photo-catalytic oxygenations in course of new functionalized polycycles, potentially new biologically active compounds.

Ključne riječi
cycloaddition; photochemistry; butadienes; benzobicyclo[3.2.1.]octadiene; polycycles

Hrčak ID: 131548

URI
https://hrcak.srce.hr/131548

Posjeta: 504 *