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https://doi.org/10.5562/cca2438

UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes

Igor Novak   ORCID icon orcid.org/0000-0002-3413-2605 ; Charles Sturt University, POB 883, Orange NSW 2800, Australia
Leo Klasinc ; Ruđer Bošković Institute, Bijenička cesta 54, HR-10000 Zagreb, Croatia;Louisiana State University, Baton Rouge LA 70803, USA
Boris Šket ; University of Ljubljana, SI-1000 Ljubljana, Slovenia
Delano P. Chong ; University of British Columbia, Vancouver, B.C. Canada V6T 1Z1
Sean P. McGlynn ; Louisiana State University, Baton Rouge LA 70803, USA

Fulltext: english, pdf (1 MB) pages 495-499 downloads: 549* cite
APA 6th Edition
Novak, I., Klasinc, L., Šket, B., Chong, D.P. & McGlynn, S.P. (2014). UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes. Croatica Chemica Acta, 87 (4), 495-499. https://doi.org/10.5562/cca2438
MLA 8th Edition
Novak, Igor, et al. "UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes." Croatica Chemica Acta, vol. 87, no. 4, 2014, pp. 495-499. https://doi.org/10.5562/cca2438. Accessed 21 Oct. 2019.
Chicago 17th Edition
Novak, Igor, Leo Klasinc, Boris Šket, Delano P. Chong and Sean P. McGlynn. "UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes." Croatica Chemica Acta 87, no. 4 (2014): 495-499. https://doi.org/10.5562/cca2438
Harvard
Novak, I., et al. (2014). 'UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes', Croatica Chemica Acta, 87(4), pp. 495-499. https://doi.org/10.5562/cca2438
Vancouver
Novak I, Klasinc L, Šket B, Chong DP, McGlynn SP. UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes. Croatica Chemica Acta [Internet]. 2014 [cited 2019 October 21];87(4):495-499. https://doi.org/10.5562/cca2438
IEEE
I. Novak, L. Klasinc, B. Šket, D.P. Chong and S.P. McGlynn, "UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes", Croatica Chemica Acta, vol.87, no. 4, pp. 495-499, 2014. [Online]. https://doi.org/10.5562/cca2438

Abstracts
The electronic structures of nine dihalobenzenes (C6H4FX; X = Cl, Br, I) have been studied by UV photoelectron spectroscopy (UPS) and assigned by comparison with the reported spectra of monoha-lobenzenes (C6H5X; X = Cl, Br, I). and quantum chemical calculations. Our results show that the fluorine substituent modifies energies of π- and halogen lone pair orbitals to a significant degree depending on its location (topology). We also demonstrate that the inductive effect of fluorine atom on the benzene ring can be readily observed and interpreted.

Keywords
halobenzenes; inductive effect; resonance effect

Hrčak ID: 131551

URI
https://hrcak.srce.hr/131551

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