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Stereochemical Aspects of Sulfoxides and Metal Sulfoxide Complexes

Mario Calligaris ; Dipartimento di Scienze Chimiche, Università di Trieste, Via L. Giorgieri 1, I-34127 Trieste, Italy

Puni tekst: engleski, pdf (130 KB) str. 147-169 preuzimanja: 936* citiraj
APA 6th Edition
Calligaris, M. (1999). Stereochemical Aspects of Sulfoxides and Metal Sulfoxide Complexes. Croatica Chemica Acta, 72 (2-3), 147-169. Preuzeto s https://hrcak.srce.hr/132154
MLA 8th Edition
Calligaris, Mario. "Stereochemical Aspects of Sulfoxides and Metal Sulfoxide Complexes." Croatica Chemica Acta, vol. 72, br. 2-3, 1999, str. 147-169. https://hrcak.srce.hr/132154. Citirano 29.03.2020.
Chicago 17th Edition
Calligaris, Mario. "Stereochemical Aspects of Sulfoxides and Metal Sulfoxide Complexes." Croatica Chemica Acta 72, br. 2-3 (1999): 147-169. https://hrcak.srce.hr/132154
Harvard
Calligaris, M. (1999). 'Stereochemical Aspects of Sulfoxides and Metal Sulfoxide Complexes', Croatica Chemica Acta, 72(2-3), str. 147-169. Preuzeto s: https://hrcak.srce.hr/132154 (Datum pristupa: 29.03.2020.)
Vancouver
Calligaris M. Stereochemical Aspects of Sulfoxides and Metal Sulfoxide Complexes. Croatica Chemica Acta [Internet]. 1999 [pristupljeno 29.03.2020.];72(2-3):147-169. Dostupno na: https://hrcak.srce.hr/132154
IEEE
M. Calligaris, "Stereochemical Aspects of Sulfoxides and Metal Sulfoxide Complexes", Croatica Chemica Acta, vol.72, br. 2-3, str. 147-169, 1999. [Online]. Dostupno na: https://hrcak.srce.hr/132154. [Citirano: 29.03.2020.]

Sažetak
Structural parameters of free and metal coordinated sulfoxides are reviewed and updated average values are derived. For uncoordinated sulfoxides, the average S−O bond distance is 1.4918(9) Å. This value is lengthened to 1.528(1) Å upon O-coordination to metal ions, while it is reduced to 1.4731(6) Å upon S-coordination. The sulfoxide bonding and bridging modes are discussed together with some stereochemical features.

Ključne riječi
sulfoxide; metal complexes; crystal structures; stereo-chemistry; average dimensions

Hrčak ID: 132154

URI
https://hrcak.srce.hr/132154

Posjeta: 1.078 *