hrcak mascot   Srce   HID

Izvorni znanstveni članak

Synthesis and Crystal and Molecular Structure of trans-[PtCl2(8-dqmp)2]* (8-dqmp = diethyl 8-quinolylmethylphosphonate)

Ivanka Matijašić ; Laboratory of Organic Chemistry, Faculty of Science, University of Zagreb, Strossmayerov trg 14, 10000 Zagreb, Croatia
Gabriele Bocelli ; Centro di Studio per la Strutturistica Diffrattometrica del CNR, Università di Parma, Viale delle Science, 43100 Parma, Italia
Corrado Rizzoli ; Centro di Studio per la Strutturistica Diffrattometrica del CNR, Università di Parma, Viale delle Science, 43100 Parma, Italia
Ljerka Tušek-Božić ; Ruđer Bošković Institute, Bijenička cesta 54, 10000 Zagreb, Croatia

Puni tekst: engleski, pdf (82 KB) str. 531-539 preuzimanja: 155* citiraj
APA 6th Edition
Matijašić, I., Bocelli, G., Rizzoli, C. i Tušek-Božić, Lj. (1999). Synthesis and Crystal and Molecular Structure of trans-[PtCl2(8-dqmp)2]* (8-dqmp = diethyl 8-quinolylmethylphosphonate). Croatica Chemica Acta, 72 (2-3), 531-539. Preuzeto s https://hrcak.srce.hr/132232
MLA 8th Edition
Matijašić, Ivanka, et al. "Synthesis and Crystal and Molecular Structure of trans-[PtCl2(8-dqmp)2]* (8-dqmp = diethyl 8-quinolylmethylphosphonate)." Croatica Chemica Acta, vol. 72, br. 2-3, 1999, str. 531-539. https://hrcak.srce.hr/132232. Citirano 05.04.2020.
Chicago 17th Edition
Matijašić, Ivanka, Gabriele Bocelli, Corrado Rizzoli i Ljerka Tušek-Božić. "Synthesis and Crystal and Molecular Structure of trans-[PtCl2(8-dqmp)2]* (8-dqmp = diethyl 8-quinolylmethylphosphonate)." Croatica Chemica Acta 72, br. 2-3 (1999): 531-539. https://hrcak.srce.hr/132232
Harvard
Matijašić, I., et al. (1999). 'Synthesis and Crystal and Molecular Structure of trans-[PtCl2(8-dqmp)2]* (8-dqmp = diethyl 8-quinolylmethylphosphonate)', Croatica Chemica Acta, 72(2-3), str. 531-539. Preuzeto s: https://hrcak.srce.hr/132232 (Datum pristupa: 05.04.2020.)
Vancouver
Matijašić I, Bocelli G, Rizzoli C, Tušek-Božić Lj. Synthesis and Crystal and Molecular Structure of trans-[PtCl2(8-dqmp)2]* (8-dqmp = diethyl 8-quinolylmethylphosphonate). Croatica Chemica Acta [Internet]. 1999 [pristupljeno 05.04.2020.];72(2-3):531-539. Dostupno na: https://hrcak.srce.hr/132232
IEEE
I. Matijašić, G. Bocelli, C. Rizzoli i Lj. Tušek-Božić, "Synthesis and Crystal and Molecular Structure of trans-[PtCl2(8-dqmp)2]* (8-dqmp = diethyl 8-quinolylmethylphosphonate)", Croatica Chemica Acta, vol.72, br. 2-3, str. 531-539, 1999. [Online]. Dostupno na: https://hrcak.srce.hr/132232. [Citirano: 05.04.2020.]

Sažetak
The complex trans-PtCl2(8-dqmp)2 – trans-dichloro-bis(diethyl 8-quinolylmethylphosphonate-κN)platinum(II) – has been synthesized and the molecular structure has been determined by a rystallographic study. The platinum atom has a slightly distorted trans square-planar configuration with Pt1–N1 = 2.042(4) and Pt1–Cl1 = 2.306(1) Å. The dihedral angle between the Pt coordination plane and the mean plane of the 8-quinolylmethyl moiety is 65.1(1)°. The complex reveals a very interesting feature: a very short methylene proton–platinum distance of 2.309(5) Å occupying approximately axial positions around the central metal atom for the hydrogen atom H10B. Refinement was performed by least-squares methods to a final R value of 3.02%.

Ključne riječi
X-ray structure; platinum(II) complex; diethyl 8-quinolylmethylphosphonate; Pt–H interaction

Hrčak ID: 132232

URI
https://hrcak.srce.hr/132232

Posjeta: 265 *