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On the Hydrogen Bonding of Succinimide Derivatives: Crystal Structure of 3(4-Pyridil-methyl)amino-pyrrolidine-2,5-dione

Gyula Argay ; Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, H-1525 Budapest 114, P.O.Box 17, Hungary
László Fábián ; Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, H-1525 Budapest 114, P.O.Box 17, Hungary
Alajos Kálmán ; Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, H-1525 Budapest 114, P.O.Box 17, Hungary

Puni tekst: engleski, pdf (391 KB) str. 551-565 preuzimanja: 298* citiraj
APA 6th Edition
Argay, G., Fábián, L. i Kálmán, A. (1999). On the Hydrogen Bonding of Succinimide Derivatives: Crystal Structure of 3(4-Pyridil-methyl)amino-pyrrolidine-2,5-dione. Croatica Chemica Acta, 72 (2-3), 551-565. Preuzeto s https://hrcak.srce.hr/132238
MLA 8th Edition
Argay, Gyula, et al. "On the Hydrogen Bonding of Succinimide Derivatives: Crystal Structure of 3(4-Pyridil-methyl)amino-pyrrolidine-2,5-dione." Croatica Chemica Acta, vol. 72, br. 2-3, 1999, str. 551-565. https://hrcak.srce.hr/132238. Citirano 31.03.2020.
Chicago 17th Edition
Argay, Gyula, László Fábián i Alajos Kálmán. "On the Hydrogen Bonding of Succinimide Derivatives: Crystal Structure of 3(4-Pyridil-methyl)amino-pyrrolidine-2,5-dione." Croatica Chemica Acta 72, br. 2-3 (1999): 551-565. https://hrcak.srce.hr/132238
Harvard
Argay, G., Fábián, L., i Kálmán, A. (1999). 'On the Hydrogen Bonding of Succinimide Derivatives: Crystal Structure of 3(4-Pyridil-methyl)amino-pyrrolidine-2,5-dione', Croatica Chemica Acta, 72(2-3), str. 551-565. Preuzeto s: https://hrcak.srce.hr/132238 (Datum pristupa: 31.03.2020.)
Vancouver
Argay G, Fábián L, Kálmán A. On the Hydrogen Bonding of Succinimide Derivatives: Crystal Structure of 3(4-Pyridil-methyl)amino-pyrrolidine-2,5-dione. Croatica Chemica Acta [Internet]. 1999 [pristupljeno 31.03.2020.];72(2-3):551-565. Dostupno na: https://hrcak.srce.hr/132238
IEEE
G. Argay, L. Fábián i A. Kálmán, "On the Hydrogen Bonding of Succinimide Derivatives: Crystal Structure of 3(4-Pyridil-methyl)amino-pyrrolidine-2,5-dione", Croatica Chemica Acta, vol.72, br. 2-3, str. 551-565, 1999. [Online]. Dostupno na: https://hrcak.srce.hr/132238. [Citirano: 31.03.2020.]

Sažetak
The structure of 3(4-pyridil-methyl)amino-pyrrolidine-2,5-dione has been established by X-ray crystallography from diffractometer data with an F2 refinement to R = 0.0526 for 1999 observed reflections. The close packing of orthorhombic crystals space group Pbca (No. 61) with a = 11.595(4), b = 8.325(1), c = 20.452(4) Å, V = 1974.2(8) Å3, Z = 8, Dc = 1.381 Mg/m3, m = 0.824 mm–1 is built of herringbone-like molecular layers folded along the c axis and fused together by infinite chains of NH⋅⋅⋅O and NH⋅⋅⋅N hydrogen bonds perpendicular to one another. This prompted us to review and characterize the hydrogen bond networks formed by succinimides possessing an unsubstituted >NH group by the use of the Cambridge Structural Database (CSD), and our own earlier structure determinations. The common motifs of the hydrogen bond systems are analyzed using graph descriptions suggested by M. C. Etter. The influence of the hydrogen bonds on molecular close packing is also discussed.

Ključne riječi
X-ray structure; hydrogen bonds; succinimides

Hrčak ID: 132238

URI
https://hrcak.srce.hr/132238

Posjeta: 403 *