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Algebraic Characterization of Simple Transition-Metal Molecules

Ray Hefferlin
Ken Luk

Puni tekst: engleski, pdf (159 KB) str. 227-232 preuzimanja: 520* citiraj
APA 6th Edition
Hefferlin, R. i Luk, K. (2007). Algebraic Characterization of Simple Transition-Metal Molecules. Croatica Chemica Acta, 80 (2), 227-232. Preuzeto s https://hrcak.srce.hr/12860
MLA 8th Edition
Hefferlin, Ray i Ken Luk. "Algebraic Characterization of Simple Transition-Metal Molecules." Croatica Chemica Acta, vol. 80, br. 2, 2007, str. 227-232. https://hrcak.srce.hr/12860. Citirano 06.12.2019.
Chicago 17th Edition
Hefferlin, Ray i Ken Luk. "Algebraic Characterization of Simple Transition-Metal Molecules." Croatica Chemica Acta 80, br. 2 (2007): 227-232. https://hrcak.srce.hr/12860
Harvard
Hefferlin, R., i Luk, K. (2007). 'Algebraic Characterization of Simple Transition-Metal Molecules', Croatica Chemica Acta, 80(2), str. 227-232. Preuzeto s: https://hrcak.srce.hr/12860 (Datum pristupa: 06.12.2019.)
Vancouver
Hefferlin R, Luk K. Algebraic Characterization of Simple Transition-Metal Molecules. Croatica Chemica Acta [Internet]. 2007 [pristupljeno 06.12.2019.];80(2):227-232. Dostupno na: https://hrcak.srce.hr/12860
IEEE
R. Hefferlin i K. Luk, "Algebraic Characterization of Simple Transition-Metal Molecules", Croatica Chemica Acta, vol.80, br. 2, str. 227-232, 2007. [Online]. Dostupno na: https://hrcak.srce.hr/12860. [Citirano: 06.12.2019.]

Sažetak
This work extends previous studies of molecules with main-group atoms to those also containing transition-metal atoms. The maximum oxidation states of group 3 to 7 atoms are succinctly described by the same algebraic equation that applies to ionically-bonded main-group atoms in molecules. Covalently bonded transition-metal molecules are characterized by the same equations that apply to main-group species, except that the octet rule is supplemented by the rule of 18, and a proposed rule of 12. Examples are given of organo-metallics with simple ligands and of transition-metal atoms in p-ring sandwiches. The solutions for a special case of the same equations apply to the gas-phase diatomic species which are of such importance in stellar and planetary atmospheres and in combustion devices.

Ključne riječi
transition-metal molecules; closed-shell molecules; rule of 18; oxidation states; algebra

Hrčak ID: 12860

URI
https://hrcak.srce.hr/12860

Posjeta: 738 *