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Electrochemical Reduction of 2-(2-Thiazolylazo)-p-cresol at a Pyrolytic Graphite Electrode

Rajendra N. Goyal ; Department of Chemistry, University ofRoorkee, Roorkee-247 667, India
Neeraj Kumar ; Department of Chemistry, University ofRoorkee, Roorkee-247 667, India

Puni tekst: engleski, pdf (16 MB) str. 925-939 preuzimanja: 111* citiraj
APA 6th Edition
Goyal, R.N. i Kumar, N. (1997). Electrochemical Reduction of 2-(2-Thiazolylazo)-p-cresol at a Pyrolytic Graphite Electrode. Croatica Chemica Acta, 70 (4), 925-939. Preuzeto s https://hrcak.srce.hr/135663
MLA 8th Edition
Goyal, Rajendra N. i Neeraj Kumar. "Electrochemical Reduction of 2-(2-Thiazolylazo)-p-cresol at a Pyrolytic Graphite Electrode." Croatica Chemica Acta, vol. 70, br. 4, 1997, str. 925-939. https://hrcak.srce.hr/135663. Citirano 24.11.2020.
Chicago 17th Edition
Goyal, Rajendra N. i Neeraj Kumar. "Electrochemical Reduction of 2-(2-Thiazolylazo)-p-cresol at a Pyrolytic Graphite Electrode." Croatica Chemica Acta 70, br. 4 (1997): 925-939. https://hrcak.srce.hr/135663
Harvard
Goyal, R.N., i Kumar, N. (1997). 'Electrochemical Reduction of 2-(2-Thiazolylazo)-p-cresol at a Pyrolytic Graphite Electrode', Croatica Chemica Acta, 70(4), str. 925-939. Preuzeto s: https://hrcak.srce.hr/135663 (Datum pristupa: 24.11.2020.)
Vancouver
Goyal RN, Kumar N. Electrochemical Reduction of 2-(2-Thiazolylazo)-p-cresol at a Pyrolytic Graphite Electrode. Croatica Chemica Acta [Internet]. 1997 [pristupljeno 24.11.2020.];70(4):925-939. Dostupno na: https://hrcak.srce.hr/135663
IEEE
R.N. Goyal i N. Kumar, "Electrochemical Reduction of 2-(2-Thiazolylazo)-p-cresol at a Pyrolytic Graphite Electrode", Croatica Chemica Acta, vol.70, br. 4, str. 925-939, 1997. [Online]. Dostupno na: https://hrcak.srce.hr/135663. [Citirano: 24.11.2020.]

Sažetak
The electrochemical reduction of 2-(2-thiazolylazo)-p-cresol has been studied in phosphate buffers of different pH at a pyrolytic graphite electrode. The reduction of the dye occurred in a single well-defined 4e, 4H+ step and the electrode reaction was found as ECE. The reduction products were separated and characterized by m.p., 1H-NMR and mass spectra. The hydrazo intermediate was found to be unstable and undergoes further reaction, the rate of which obeys the equation rate = r° + k}j [H+] + &QH [OH-].

Hrčak ID: 135663

URI
https://hrcak.srce.hr/135663

Posjeta: 197 *