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Structure, Dynamics and Vibrational Spectra of α-Chloroallyl Cations in Solid SbF5-Matrices

Hrvoj Vančik ; University of Zagreb, Faculty of Science, Department of Chemistry, Strossmayerov trg 14, 10000 Zagreb, Croatia
Zlatko Mihalić ; University of Zagreb, Faculty of Science, Department of Chemistry, Strossmayerov trg 14, 10000 Zagreb, Croatia
Davor Kiđemet ; University of Zagreb, Faculty of Science, Department of Chemistry, Strossmayerov trg 14, 10000 Zagreb, Croatia

Puni tekst: engleski, pdf (8 MB) str. 1511-1520 preuzimanja: 242* citiraj
APA 6th Edition
Vančik, H., Mihalić, Z. i Kiđemet, D. (1996). Structure, Dynamics and Vibrational Spectra of α-Chloroallyl Cations in Solid SbF5-Matrices. Croatica Chemica Acta, 69 (4), 1511-1520. Preuzeto s https://hrcak.srce.hr/135987
MLA 8th Edition
Vančik, Hrvoj, et al. "Structure, Dynamics and Vibrational Spectra of α-Chloroallyl Cations in Solid SbF5-Matrices." Croatica Chemica Acta, vol. 69, br. 4, 1996, str. 1511-1520. https://hrcak.srce.hr/135987. Citirano 07.03.2021.
Chicago 17th Edition
Vančik, Hrvoj, Zlatko Mihalić i Davor Kiđemet. "Structure, Dynamics and Vibrational Spectra of α-Chloroallyl Cations in Solid SbF5-Matrices." Croatica Chemica Acta 69, br. 4 (1996): 1511-1520. https://hrcak.srce.hr/135987
Harvard
Vančik, H., Mihalić, Z., i Kiđemet, D. (1996). 'Structure, Dynamics and Vibrational Spectra of α-Chloroallyl Cations in Solid SbF5-Matrices', Croatica Chemica Acta, 69(4), str. 1511-1520. Preuzeto s: https://hrcak.srce.hr/135987 (Datum pristupa: 07.03.2021.)
Vancouver
Vančik H, Mihalić Z, Kiđemet D. Structure, Dynamics and Vibrational Spectra of α-Chloroallyl Cations in Solid SbF5-Matrices. Croatica Chemica Acta [Internet]. 1996 [pristupljeno 07.03.2021.];69(4):1511-1520. Dostupno na: https://hrcak.srce.hr/135987
IEEE
H. Vančik, Z. Mihalić i D. Kiđemet, "Structure, Dynamics and Vibrational Spectra of α-Chloroallyl Cations in Solid SbF5-Matrices", Croatica Chemica Acta, vol.69, br. 4, str. 1511-1520, 1996. [Online]. Dostupno na: https://hrcak.srce.hr/135987. [Citirano: 07.03.2021.]

Sažetak
Cis- and frans-α-chloroallyl cations were prepared by matrix isolation method in solid SbF5 matrix, and obtained FT-IR spectra compared with the results of high-level ab-initio calculations. Ionization of either cis- or trans-1,3-dichloropropenes lead to the mixture of cis- and trans-cations, whose interconversion barrier is smaller than for parent allyl cation. The extent of a-chlorine carbocation stabilization was shown to be comparable to that obtained by methyl group. Additionally, the ionization constant of chloro- propenes in the solid SbF5 matrix was measured for the first time.

Hrčak ID: 135987

URI
https://hrcak.srce.hr/135987

Posjeta: 342 *