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Reactivity of Some Tertiary Chlorides with Methoxy and Olefinic Neighboring Group

Stanko Borčić ; Faculty of Pharmacy and Biochemistry, University of Zagreb, A. Kovačića 1, P. 0. Box 156, 10000 Zagreb, Croatia
Olga Kronja ; Faculty of Pharmacy and Biochemistry, University of Zagreb, A. Kovačića 1, P. 0. Box 156, 10000 Zagreb, Croatia
Krešimir Humski ; Faculty of Pharmacy and Biochemistry, University of Zagreb, A. Kovačića 1, P. 0. Box 156, 10000 Zagreb, Croatia
Sandra Miletić ; Faculty of Pharmacy and Biochemistry, University of Zagreb, A. Kovačića 1, P. 0. Box 156, 10000 Zagreb, Croatia

Puni tekst: engleski, pdf (14 MB) str. 563-568 preuzimanja: 159* citiraj
APA 6th Edition
Borčić, S., Kronja, O., Humski, K. i Miletić, S. (1996). Reactivity of Some Tertiary Chlorides with Methoxy and Olefinic Neighboring Group. Croatica Chemica Acta, 69 (2), 563-568. Preuzeto s https://hrcak.srce.hr/136672
MLA 8th Edition
Borčić, Stanko, et al. "Reactivity of Some Tertiary Chlorides with Methoxy and Olefinic Neighboring Group." Croatica Chemica Acta, vol. 69, br. 2, 1996, str. 563-568. https://hrcak.srce.hr/136672. Citirano 26.02.2021.
Chicago 17th Edition
Borčić, Stanko, Olga Kronja, Krešimir Humski i Sandra Miletić. "Reactivity of Some Tertiary Chlorides with Methoxy and Olefinic Neighboring Group." Croatica Chemica Acta 69, br. 2 (1996): 563-568. https://hrcak.srce.hr/136672
Harvard
Borčić, S., et al. (1996). 'Reactivity of Some Tertiary Chlorides with Methoxy and Olefinic Neighboring Group', Croatica Chemica Acta, 69(2), str. 563-568. Preuzeto s: https://hrcak.srce.hr/136672 (Datum pristupa: 26.02.2021.)
Vancouver
Borčić S, Kronja O, Humski K, Miletić S. Reactivity of Some Tertiary Chlorides with Methoxy and Olefinic Neighboring Group. Croatica Chemica Acta [Internet]. 1996 [pristupljeno 26.02.2021.];69(2):563-568. Dostupno na: https://hrcak.srce.hr/136672
IEEE
S. Borčić, O. Kronja, K. Humski i S. Miletić, "Reactivity of Some Tertiary Chlorides with Methoxy and Olefinic Neighboring Group", Croatica Chemica Acta, vol.69, br. 2, str. 563-568, 1996. [Online]. Dostupno na: https://hrcak.srce.hr/136672. [Citirano: 26.02.2021.]

Sažetak
Solvolysis rates of tertiary chlorides 1-6 and their hexadeuterated analogs 1-dg-6-đe were measured in ethanol (q> = 80%) and 2,2,2- trifluoroethanol (w = 97%). The (5-deuterium KIE calculated showed that chloride 1 solvolyzes with n-participation of the methoxy group in the rate determining step, while chloride 2 solvolyzes mainly by way of a kc process. Based on the reduced P-deuterium isotope effect, it was also concluded that in the solvolysis of chloride 5 7t-electrons take part in the rate-determining step.

Hrčak ID: 136672

URI
https://hrcak.srce.hr/136672

Posjeta: 280 *