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Croatica Chemica Acta, Vol. 69 No. 2, 1996.

Izvorni znanstveni članak

Transformation of a Racemic Mixture by a Chiral Reagent or Catalyst to Give Regioisomeric Products

Henri B. Kagan ; Laboratoire de Synthèse Asymétrique Associé au CNRS, Institut de Chimie Moléculaire d'Orsay, Université Paris-Sud, 91405 Orsay cedex, France

Puni tekst: engleski, pdf (25 MB) str. 669-680 preuzimanja: 298* citiraj
APA 6th Edition
Kagan, H.B. (1996). Transformation of a Racemic Mixture by a Chiral Reagent or Catalyst to Give Regioisomeric Products. Croatica Chemica Acta, 69 (2), 669-680. Preuzeto s https://hrcak.srce.hr/136678
MLA 8th Edition
Kagan, Henri B.. "Transformation of a Racemic Mixture by a Chiral Reagent or Catalyst to Give Regioisomeric Products." Croatica Chemica Acta, vol. 69, br. 2, 1996, str. 669-680. https://hrcak.srce.hr/136678. Citirano 05.03.2021.
Chicago 17th Edition
Kagan, Henri B.. "Transformation of a Racemic Mixture by a Chiral Reagent or Catalyst to Give Regioisomeric Products." Croatica Chemica Acta 69, br. 2 (1996): 669-680. https://hrcak.srce.hr/136678
Harvard
Kagan, H.B. (1996). 'Transformation of a Racemic Mixture by a Chiral Reagent or Catalyst to Give Regioisomeric Products', Croatica Chemica Acta, 69(2), str. 669-680. Preuzeto s: https://hrcak.srce.hr/136678 (Datum pristupa: 05.03.2021.)
Vancouver
Kagan HB. Transformation of a Racemic Mixture by a Chiral Reagent or Catalyst to Give Regioisomeric Products. Croatica Chemica Acta [Internet]. 1996 [pristupljeno 05.03.2021.];69(2):669-680. Dostupno na: https://hrcak.srce.hr/136678
IEEE
H.B. Kagan, "Transformation of a Racemic Mixture by a Chiral Reagent or Catalyst to Give Regioisomeric Products", Croatica Chemica Acta, vol.69, br. 2, str. 669-680, 1996. [Online]. Dostupno na: https://hrcak.srce.hr/136678. [Citirano: 05.03.2021.]

Sažetak
The transformation of a racemic mixture under the influence of a chiral reagent or catalyst is discussed in the case where regioisomeric products are obtained. The general relationships correlating the ee's and the quantities of the various products are given.
The special case of asymmetric Baeyer-Villiger oxidation of racemic ketones is taken as an example. Sometimes regioisomeric products are derived from opposite enantiomers, which implies that the re- gioselectivity of a reaction on an enantiomerically pure starting material will be controlled by the absolute configuration of the chiral reagent or catalyst.

Hrčak ID: 136678

URI
https://hrcak.srce.hr/136678

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