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Croatica Chemica Acta, Vol. 68 No. 4, 1995

Original scientific paper

Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]

D. Michael P. Mingos ; Chemistry Department, Imperial College of Science, Technology and Medicine, South Kensington, London SW7 2AY, United Kingdom
Christopher M. Hill ; Chemistry Department, Imperial College of Science, Technology and Medicine, South Kensington, London SW7 2AY, United Kingdom

Fulltext: english, pdf (7 MB) pages 745-767 downloads: 177* cite
APA 6th Edition
Mingos, D.M.P. & Hill, C.M. (1995). Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]. Croatica Chemica Acta, 68 (4), 745-767. Retrieved from https://hrcak.srce.hr/136691
MLA 8th Edition
Mingos, D. Michael P. and Christopher M. Hill. "Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]." Croatica Chemica Acta, vol. 68, no. 4, 1995, pp. 745-767. https://hrcak.srce.hr/136691. Accessed 23 Apr. 2021.
Chicago 17th Edition
Mingos, D. Michael P. and Christopher M. Hill. "Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]." Croatica Chemica Acta 68, no. 4 (1995): 745-767. https://hrcak.srce.hr/136691
Harvard
Mingos, D.M.P., and Hill, C.M. (1995). 'Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]', Croatica Chemica Acta, 68(4), pp. 745-767. Available at: https://hrcak.srce.hr/136691 (Accessed 23 April 2021)
Vancouver
Mingos DMP, Hill CM. Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]. Croatica Chemica Acta [Internet]. 1995 [cited 2021 April 23];68(4):745-767. Available from: https://hrcak.srce.hr/136691
IEEE
D.M.P. Mingos and C.M. Hill, "Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]", Croatica Chemica Acta, vol.68, no. 4, pp. 745-767, 1995. [Online]. Available: https://hrcak.srce.hr/136691. [Accessed: 23 April 2021]

Abstracts
The decanuclear palladium cluster compounds [Pdio(u-CO)g(^3-CO)4 (PEtglg] and [Pdio(/(-CO)g(ii3-CO)2(//-CNXyl)2(PEt3)g] (Xyl = CgH^M^- 2,6) have been synthesised and characterised by a combination of spectroscopic data and single crystal X-ray crystallographic analyses. The former has a distorted tetracapped octahedral skeletal geometry and the latter a hexacapped tetrahedral geometry. The latter is unique in cluster chemistry and the structural change induced by the addition of isocyanide represents an interesting example of the effect of the steric requirements of the isocyanide ligand influencing the total electron count and geometry of the cluster. [Pdio(/<-CO)8(/i3-CO)4(PEt3)g] reacts with SO2 to give [Pd5(/(-S02)2(p3-S02)2(PEt3)5].

Hrčak ID: 136691

URI
https://hrcak.srce.hr/136691

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