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Self Assembly of Copper(I) and Silver(I) Butterfly Clusters with 2-Mercaptothiazoline

César A. López ; Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A&M University, College Station, TX 77843-3255, USA
John P., Jr. Fackler ; Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A&M University, College Station, TX 77843-3255, USA
Richard J. Staples ; Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A&M University, College Station, TX 77843-3255, USA
Suning Wang ; Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A&M University, College Station, TX 77843-3255, USA
Richard E. P. Winpenny ; Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A&M University, College Station, TX 77843-3255, USA

Puni tekst: engleski, pdf (6 MB) str. 793-823 preuzimanja: 145* citiraj
APA 6th Edition
López, C.A., Fackler, J.P.,.J., Staples, R.J., Wang, S. i Winpenny, R.E.P. (1995). Self Assembly of Copper(I) and Silver(I) Butterfly Clusters with 2-Mercaptothiazoline. Croatica Chemica Acta, 68 (4), 793-823. Preuzeto s https://hrcak.srce.hr/136694
MLA 8th Edition
López, César A., et al. "Self Assembly of Copper(I) and Silver(I) Butterfly Clusters with 2-Mercaptothiazoline." Croatica Chemica Acta, vol. 68, br. 4, 1995, str. 793-823. https://hrcak.srce.hr/136694. Citirano 02.03.2021.
Chicago 17th Edition
López, César A., John P., Jr. Fackler, Richard J. Staples, Suning Wang i Richard E. P. Winpenny. "Self Assembly of Copper(I) and Silver(I) Butterfly Clusters with 2-Mercaptothiazoline." Croatica Chemica Acta 68, br. 4 (1995): 793-823. https://hrcak.srce.hr/136694
Harvard
López, C.A., et al. (1995). 'Self Assembly of Copper(I) and Silver(I) Butterfly Clusters with 2-Mercaptothiazoline', Croatica Chemica Acta, 68(4), str. 793-823. Preuzeto s: https://hrcak.srce.hr/136694 (Datum pristupa: 02.03.2021.)
Vancouver
López CA, Fackler JP,J, Staples RJ, Wang S, Winpenny REP. Self Assembly of Copper(I) and Silver(I) Butterfly Clusters with 2-Mercaptothiazoline. Croatica Chemica Acta [Internet]. 1995 [pristupljeno 02.03.2021.];68(4):793-823. Dostupno na: https://hrcak.srce.hr/136694
IEEE
C.A. López, J.P.,.J. Fackler, R.J. Staples, S. Wang i R.E.P. Winpenny, "Self Assembly of Copper(I) and Silver(I) Butterfly Clusters with 2-Mercaptothiazoline", Croatica Chemica Acta, vol.68, br. 4, str. 793-823, 1995. [Online]. Dostupno na: https://hrcak.srce.hr/136694. [Citirano: 02.03.2021.]

Sažetak
X-ray data obtained from poor crystals which formed from the reaction of copper(II) acetate with 2-mercaptothiazoline reveal the formation of a product that is a polymer formed of tetranuclear, butterfly shaped Cu4(MT)4, 1, clusters. Preparation, isolation and structural characterization of a series of isostructural butterfly complexes was accomplished by addition of a Lewis base (pyridine,
PPh3, or ASPI13) to the precipitate obtained from the reaction of copper(II) and/or silver(I) acetate with the appropriate stoichiometric amount of 2-mercaptothiazoline. The general formula of these clusters is L2M4(MT)4; 2, L = PPI13 and M = Cu; 3, L = AsPh3 and M = Cu; 6, L = PPI13 and M = Ag; MT = C3H4NS2_, known as 2-mer- captothiazolinate. The polymer [pyCu4(MT)4]„, 4, formed by the addition of pyridine to 1, was also characterized crystallographically.
A mixed metal butterfly complex, (PPh3)2Ag2Cu2(MT)4, 8, is formed by addition of PPI13 to a suspension of the precipitate formed upon reaction of the free HMT ligand with a 1:1 mixture of copper(II) and silver(I) acetates in CH2CI2. FD-MS results of each of the precipitates obtained from the metal acetates and the free ligand indicate that the monomeric unit is M4(MT)4. 1H-NMR and 31P{1H}-NMR, both in solution and in the solid state are presented and interpreted.

Hrčak ID: 136694

URI
https://hrcak.srce.hr/136694

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