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Original scientific paper

Synthesis, Crystal Structures and Properties of New Chloroniobium Cluster Hydroxides with Co-ordinated and Non-coordinated OH- Groups. The Presence of H3O2 Intercluster Bridges

Nevenka Brničević ; Ruđer Bošković Institute, P. O. Box 1016, 10000 Zagreb, Croatia
Biserka Kojić-Prodić ; Ruđer Bošković Institute, P. O. Box 1016, 10000 Zagreb, Croatia
Marija Luić ; Ruđer Bošković Institute, P. O. Box 1016, 10000 Zagreb, Croatia
Aziz Kashta ; Ruđer Bošković Institute, P. O. Box 1016, 10000 Zagreb, Croatia
Pavica Planinić ; Ruđer Bošković Institute, P. O. Box 1016, 10000 Zagreb, Croatia
Robert E. McCarley ; Arnes Laboratory, USDOE and Department of Chemistry, Iowa State University, Ames, Iowa 50011, U.S.A.

Fulltext: english, pdf (33 MB) pages 861-875 downloads: 126* cite
APA 6th Edition
Brničević, N., Kojić-Prodić, B., Luić, M., Kashta, A., Planinić, P. & McCarley, R.E. (1995). Synthesis, Crystal Structures and Properties of New Chloroniobium Cluster Hydroxides with Co-ordinated and Non-coordinated OH- Groups. The Presence of H3O2 Intercluster Bridges. Croatica Chemica Acta, 68 (4), 861-875. Retrieved from https://hrcak.srce.hr/136698
MLA 8th Edition
Brničević, Nevenka, et al. "Synthesis, Crystal Structures and Properties of New Chloroniobium Cluster Hydroxides with Co-ordinated and Non-coordinated OH- Groups. The Presence of H3O2 Intercluster Bridges." Croatica Chemica Acta, vol. 68, no. 4, 1995, pp. 861-875. https://hrcak.srce.hr/136698. Accessed 20 Apr. 2021.
Chicago 17th Edition
Brničević, Nevenka, Biserka Kojić-Prodić, Marija Luić, Aziz Kashta, Pavica Planinić and Robert E. McCarley. "Synthesis, Crystal Structures and Properties of New Chloroniobium Cluster Hydroxides with Co-ordinated and Non-coordinated OH- Groups. The Presence of H3O2 Intercluster Bridges." Croatica Chemica Acta 68, no. 4 (1995): 861-875. https://hrcak.srce.hr/136698
Harvard
Brničević, N., et al. (1995). 'Synthesis, Crystal Structures and Properties of New Chloroniobium Cluster Hydroxides with Co-ordinated and Non-coordinated OH- Groups. The Presence of H3O2 Intercluster Bridges', Croatica Chemica Acta, 68(4), pp. 861-875. Available at: https://hrcak.srce.hr/136698 (Accessed 20 April 2021)
Vancouver
Brničević N, Kojić-Prodić B, Luić M, Kashta A, Planinić P, McCarley RE. Synthesis, Crystal Structures and Properties of New Chloroniobium Cluster Hydroxides with Co-ordinated and Non-coordinated OH- Groups. The Presence of H3O2 Intercluster Bridges. Croatica Chemica Acta [Internet]. 1995 [cited 2021 April 20];68(4):861-875. Available from: https://hrcak.srce.hr/136698
IEEE
N. Brničević, B. Kojić-Prodić, M. Luić, A. Kashta, P. Planinić and R.E. McCarley, "Synthesis, Crystal Structures and Properties of New Chloroniobium Cluster Hydroxides with Co-ordinated and Non-coordinated OH- Groups. The Presence of H3O2 Intercluster Bridges", Croatica Chemica Acta, vol.68, no. 4, pp. 861-875, 1995. [Online]. Available: https://hrcak.srce.hr/136698. [Accessed: 20 April 2021]

Abstracts
The isostructural, trigonal clusters of the composition [Nb6Cl12(H20)6](0H)2 l/4CH30H • 6H20 1 and [Nb6Cl12(H20)6](OH)2 -6H20 2 have been isolated from alkaline solutions of [NbgClj^]2* cluster in alcohol/water (1:3) in the presence of NMe^H, while the presence of NEt^H yielded NEt^NbeCl^Hjjf^e^IS^O 3. Compound 1 crystallizes in trigonal space group R3m with a = 21.166(5) A and c = 23.812(4) Å, y = 120°, U = 9238.6(3) Å3, Z = 12. Two ciystal- lographically independent cluster octahedra (I and II) have been found in the unit cell of 1 in the ratio 3:1. The Nb-0 distances of 2.211(11) Å and 2.217(16) Å for I and 2.238(19) Å for II indicate six co-ordinated water molecules. The cluster units of I are connected by hydrogen bonds of 2.49(1) A into a two-dimensional framework. Compound 3 is monoclinic, space group P2j/n, a = 10.085(5) A, b = 11.446(4) Å, c = 14.971(6) Å, /? = 102.95(6)°, U = 1684.2(1) Å3, Z = 2. The short Nb-O distances at 2.167(6), 2.177(8) and 2.187(7) A and considerable reduction of the Nb-O stretching frequency in the IR spectra support the presence of H302 (co-ordinated water molecule from one cluster unit and co-ordinated OH~ group from the neighbouring cluster unit) bridges. Each cluster unit is joined to the six neighbouring units by intermolecular hydrogen bonds of distances 2.540(11) Å and 2.594(10) Å in a three-dimensional network.

Hrčak ID: 136698

URI
https://hrcak.srce.hr/136698

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