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Solvolysis of 1-(3-Noradamantyl)-2-methylpropyl and 1-(3-Noradamantyl)-2,2-dimethylpropyl Pemsylates

D. T. Stoelting ; Department of Chemistry, Indiana University, Bloomington, Indiana 47405
V. J. Shiner, Jr. ; Department of Chemistry, Indiana University, Bloomington, Indiana 47405

Puni tekst: engleski, pdf (9 MB) str. 517-538 preuzimanja: 150* citiraj
APA 6th Edition
Stoelting, D.T. i Shiner, Jr., V.J. (1992). Solvolysis of 1-(3-Noradamantyl)-2-methylpropyl and 1-(3-Noradamantyl)-2,2-dimethylpropyl Pemsylates. Croatica Chemica Acta, 65 (3), 517-538. Preuzeto s https://hrcak.srce.hr/137113
MLA 8th Edition
Stoelting, D. T. i V. J. Shiner, Jr.. "Solvolysis of 1-(3-Noradamantyl)-2-methylpropyl and 1-(3-Noradamantyl)-2,2-dimethylpropyl Pemsylates." Croatica Chemica Acta, vol. 65, br. 3, 1992, str. 517-538. https://hrcak.srce.hr/137113. Citirano 25.02.2021.
Chicago 17th Edition
Stoelting, D. T. i V. J. Shiner, Jr.. "Solvolysis of 1-(3-Noradamantyl)-2-methylpropyl and 1-(3-Noradamantyl)-2,2-dimethylpropyl Pemsylates." Croatica Chemica Acta 65, br. 3 (1992): 517-538. https://hrcak.srce.hr/137113
Harvard
Stoelting, D.T., i Shiner, Jr., V.J. (1992). 'Solvolysis of 1-(3-Noradamantyl)-2-methylpropyl and 1-(3-Noradamantyl)-2,2-dimethylpropyl Pemsylates', Croatica Chemica Acta, 65(3), str. 517-538. Preuzeto s: https://hrcak.srce.hr/137113 (Datum pristupa: 25.02.2021.)
Vancouver
Stoelting DT, Shiner, Jr. VJ. Solvolysis of 1-(3-Noradamantyl)-2-methylpropyl and 1-(3-Noradamantyl)-2,2-dimethylpropyl Pemsylates. Croatica Chemica Acta [Internet]. 1992 [pristupljeno 25.02.2021.];65(3):517-538. Dostupno na: https://hrcak.srce.hr/137113
IEEE
D.T. Stoelting i V.J. Shiner, Jr., "Solvolysis of 1-(3-Noradamantyl)-2-methylpropyl and 1-(3-Noradamantyl)-2,2-dimethylpropyl Pemsylates", Croatica Chemica Acta, vol.65, br. 3, str. 517-538, 1992. [Online]. Dostupno na: https://hrcak.srce.hr/137113. [Citirano: 25.02.2021.]

Sažetak
Rates, m-values, a-d and ft-d rate effects are reported for solvolyses of the title esters along with MMX calculations of the strain energies of initial and transition states. These results are compared with those from several lower homologs and related adamantyl carbinyl esters. It is found that the noradamantyl carbinyl ester solvolyses are accelerated up to 10,000-fold by C-C o-participatìon; /3-branching in
the alkyl side-chain reduces this rate effect by as much as 100-fold.

Hrčak ID: 137113

URI
https://hrcak.srce.hr/137113

Posjeta: 238 *