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Diallylic and Diallenic Dyotropic Rearrangements

Joseph B. Lambert ; Department of Chemistry, Northwestern University, Evanston, IL 60208, USA
Daniel Stec III ; Department of Chemistry, Northwestern University, Evanston, IL 60208, USA

Puni tekst: engleski, pdf (16 MB) str. 737-743 preuzimanja: 117* citiraj
APA 6th Edition
Lambert, J.B. i Stec III, D. (1992). Diallylic and Diallenic Dyotropic Rearrangements. Croatica Chemica Acta, 65 (3), 737-743. Preuzeto s https://hrcak.srce.hr/137131
MLA 8th Edition
Lambert, Joseph B. i Daniel Stec III. "Diallylic and Diallenic Dyotropic Rearrangements." Croatica Chemica Acta, vol. 65, br. 3, 1992, str. 737-743. https://hrcak.srce.hr/137131. Citirano 26.02.2021.
Chicago 17th Edition
Lambert, Joseph B. i Daniel Stec III. "Diallylic and Diallenic Dyotropic Rearrangements." Croatica Chemica Acta 65, br. 3 (1992): 737-743. https://hrcak.srce.hr/137131
Harvard
Lambert, J.B., i Stec III, D. (1992). 'Diallylic and Diallenic Dyotropic Rearrangements', Croatica Chemica Acta, 65(3), str. 737-743. Preuzeto s: https://hrcak.srce.hr/137131 (Datum pristupa: 26.02.2021.)
Vancouver
Lambert JB, Stec III D. Diallylic and Diallenic Dyotropic Rearrangements. Croatica Chemica Acta [Internet]. 1992 [pristupljeno 26.02.2021.];65(3):737-743. Dostupno na: https://hrcak.srce.hr/137131
IEEE
J.B. Lambert i D. Stec III, "Diallylic and Diallenic Dyotropic Rearrangements", Croatica Chemica Acta, vol.65, br. 3, str. 737-743, 1992. [Online]. Dostupno na: https://hrcak.srce.hr/137131. [Citirano: 26.02.2021.]

Sažetak
A previously unexamined approach to dyotropic rearrangements involving only atoms from the first row is tested with four substrates. Both migrating groups contain jr orbitals, either allylic or allenic. We have prepared 3,6- dimethyl-1,7-octadiene,1,2-bis(vinyloxy)ethane, ethylene diisocyanate, and ethylene dithiocyanate to test this approach. All four substrates were pyrolyzed in a sealed tube and in a flash system. Products of ene reactions, diradical rearrangements, cycloaddition, and polymerization were observed, but the dyotropic rearrangements did not take place.

Hrčak ID: 137131

URI
https://hrcak.srce.hr/137131

Posjeta: 211 *