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Electrocatalytically Relevant Surface Properties of Anodic Oxides: TiO2

Radoslav T. Atanasoski ; Institute of Electrochemistry ICTM and Center for Multidisciplinary Studies University of Belgrade 111001 Belgrade, Yugoslavia

Puni tekst: engleski, pdf (15 MB) str. 355-372 preuzimanja: 112* citiraj
APA 6th Edition
Atanasoski, R.T. (1990). Electrocatalytically Relevant Surface Properties of Anodic Oxides: TiO2. Croatica Chemica Acta, 63 (3), 355-372. Preuzeto s https://hrcak.srce.hr/137378
MLA 8th Edition
Atanasoski, Radoslav T.. "Electrocatalytically Relevant Surface Properties of Anodic Oxides: TiO2." Croatica Chemica Acta, vol. 63, br. 3, 1990, str. 355-372. https://hrcak.srce.hr/137378. Citirano 28.02.2021.
Chicago 17th Edition
Atanasoski, Radoslav T.. "Electrocatalytically Relevant Surface Properties of Anodic Oxides: TiO2." Croatica Chemica Acta 63, br. 3 (1990): 355-372. https://hrcak.srce.hr/137378
Harvard
Atanasoski, R.T. (1990). 'Electrocatalytically Relevant Surface Properties of Anodic Oxides: TiO2', Croatica Chemica Acta, 63(3), str. 355-372. Preuzeto s: https://hrcak.srce.hr/137378 (Datum pristupa: 28.02.2021.)
Vancouver
Atanasoski RT. Electrocatalytically Relevant Surface Properties of Anodic Oxides: TiO2. Croatica Chemica Acta [Internet]. 1990 [pristupljeno 28.02.2021.];63(3):355-372. Dostupno na: https://hrcak.srce.hr/137378
IEEE
R.T. Atanasoski, "Electrocatalytically Relevant Surface Properties of Anodic Oxides: TiO2", Croatica Chemica Acta, vol.63, br. 3, str. 355-372, 1990. [Online]. Dostupno na: https://hrcak.srce.hr/137378. [Citirano: 28.02.2021.]

Sažetak
Photoelectrochemical, electrochemical, surface structural and compositional studies of Ti||Ti02 and RuC>2||TiC>2 interface are described. Anodic TiC>2 films formed on Ti substrate revealed the presence of rutile as the only identifiable phase. A kind of epitaxial relationship between the titanium substrate and slowly grown TiC>2 films was established. Thermally applied RuC>2 on the anodic films acted as a probe for the microstructure of TiC>2.
RU02 exhibited electrooatalytic and photoelectrochemical effect on
slowly grown oxide films and showed none on step grown films.
XPS and L.EED studies of single crystal RuC>2 and RuCtellTi interface showed that vapor deposited titanium reduces the always present Ru03 on the surface layers of RuC>2. The pseudomorphism of rutile RuC>2 and Ti02 yielded eventually to an epitaxial ordering of TiC>2 overlayer. The structures of the order TIO2 overlayers at the (100) versus the (110) face of RuC>2 were interpreted by the difference in their atomic arrangement.

Hrčak ID: 137378

URI
https://hrcak.srce.hr/137378

Posjeta: 213 *