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Exciton Optical Activity of Molecules Containing Three and Six Coupled Oscillators Belonging to C3 and D3 Point Groups: Applications to Cyclotriveratrylenes and Cryptophanes

Andre Collet ; Stereochimie et Interactions motecutaires,* Ecole Normate Superieure de Lyon, 46, AlUie d'ItaHe, 69364 Lyon cedex 07, France
Giovanni Gottarelli ; Dipartimento di Chimica Organica, Universitti di Boloqna, Via S. Donato 15, 40127 Botogna, Itaty

Sažetak

The exciton model of optical activity has been applied to
C3 cyclotriveratrylenes and D3 cryptophanes, molecules containing
three and six coupled oscillators, respectively. Using this model,
in conjunction with Platt's spectroscopic moment approach, very
good agreement has been established between experimental and
calculated spectra. These results point to the importance of the
exciton model in explaining the CD spectra of molecules containing
more than two oscillators.

Ključne riječi

Hrčak ID:

175522

URI

https://hrcak.srce.hr/175522

Datum izdavanja:

10.8.1989.

Posjeta: 605 *