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Croatica Chemica Acta, Vol. 61 No. 2, 1988.

Izvorni znanstveni članak

Infrared and Raman Spectroscopy of the Dirhodium Tetraacetate Complexes Rh2(O2CCH3)4, Rh2(18O2CCH3)4, Rh2(O2CCD3)4 and Rh2(O2CCH3)4(H2O)2

Robin J. H. Clark ; Christopher Ingold Laboratories University College London 20 Gordon Street London WC1H 0AJ, U. K.
Andrew J. Hempleman ; Christopher Ingold Laboratories University College London 20 Gordon Street London WC1H 0AJ, U. K.

Puni tekst: engleski, pdf (7 MB) str. 313-329 preuzimanja: 219* citiraj
APA 6th Edition
Clark, R.J.H. i Hempleman, A.J. (1988). Infrared and Raman Spectroscopy of the Dirhodium Tetraacetate Complexes Rh2(O2CCH3)4, Rh2(18O2CCH3)4, Rh2(O2CCD3)4 and Rh2(O2CCH3)4(H2O)2. Croatica Chemica Acta, 61 (2), 313-329. Preuzeto s https://hrcak.srce.hr/175904
MLA 8th Edition
Clark, Robin J. H. i Andrew J. Hempleman. "Infrared and Raman Spectroscopy of the Dirhodium Tetraacetate Complexes Rh2(O2CCH3)4, Rh2(18O2CCH3)4, Rh2(O2CCD3)4 and Rh2(O2CCH3)4(H2O)2." Croatica Chemica Acta, vol. 61, br. 2, 1988, str. 313-329. https://hrcak.srce.hr/175904. Citirano 04.03.2021.
Chicago 17th Edition
Clark, Robin J. H. i Andrew J. Hempleman. "Infrared and Raman Spectroscopy of the Dirhodium Tetraacetate Complexes Rh2(O2CCH3)4, Rh2(18O2CCH3)4, Rh2(O2CCD3)4 and Rh2(O2CCH3)4(H2O)2." Croatica Chemica Acta 61, br. 2 (1988): 313-329. https://hrcak.srce.hr/175904
Harvard
Clark, R.J.H., i Hempleman, A.J. (1988). 'Infrared and Raman Spectroscopy of the Dirhodium Tetraacetate Complexes Rh2(O2CCH3)4, Rh2(18O2CCH3)4, Rh2(O2CCD3)4 and Rh2(O2CCH3)4(H2O)2', Croatica Chemica Acta, 61(2), str. 313-329. Preuzeto s: https://hrcak.srce.hr/175904 (Datum pristupa: 04.03.2021.)
Vancouver
Clark RJH, Hempleman AJ. Infrared and Raman Spectroscopy of the Dirhodium Tetraacetate Complexes Rh2(O2CCH3)4, Rh2(18O2CCH3)4, Rh2(O2CCD3)4 and Rh2(O2CCH3)4(H2O)2. Croatica Chemica Acta [Internet]. 1988 [pristupljeno 04.03.2021.];61(2):313-329. Dostupno na: https://hrcak.srce.hr/175904
IEEE
R.J.H. Clark i A.J. Hempleman, "Infrared and Raman Spectroscopy of the Dirhodium Tetraacetate Complexes Rh2(O2CCH3)4, Rh2(18O2CCH3)4, Rh2(O2CCD3)4 and Rh2(O2CCH3)4(H2O)2", Croatica Chemica Acta, vol.61, br. 2, str. 313-329, 1988. [Online]. Dostupno na: https://hrcak.srce.hr/175904. [Citirano: 04.03.2021.]

Sažetak
The infrared (3500-50 cm-I), and Raman (3550-30 cm-I)
spectra of the dirhodium tetraacetate species Rh2(02CCHs)4,
Rh2(IB02CCHs)4, Rh2(02CCDS)4, and Rh2(02CCHs)4(H20)2 have been recorded and the key bands assigned, The oxygen-18 and deuteration studies, in particular, assisted with ma king the important band assignments for the anhydrous complex, for which 11 (RhRh)
occurs at 355-351 cm-I, and 11 (RhO) at 389-319 cm-I (Raman) and
398-341 cm-I (infrared). The band attributed to 11 (RhRh) is typically
intense, sharp, and relatively insensitive to either IBO_ or CDs-substitution. Thus 11 (RhRh) shifts only 4 cm-Ion either IBO
or CDs substitution whereas 11 (RhO) shifts 4-6 cm-I in the Raman
and 3-7 cm-I in the infrared spectra on IBO substitution but 12
cm-I in the Raman and 11-18 cm-I in the infrared spectra on CDs
substitution. Some preliminary isotopic work for the complex
Rh2(02CCHS)4(H20l2 is also presented.

Hrčak ID: 175904

URI
https://hrcak.srce.hr/175904

Posjeta: 293 *