hrcak mascot   Srce   HID

Pregledni rad

Interpreting the eH Stretching Region, Through Infrared Partial Deuteration Studies

D. C. McKean ; Department of Chemistry, University of Aberdeen, Aberdeen AB9 2UE, UK

Puni tekst: engleski, pdf (7 MB) str. 447-461 preuzimanja: 80* citiraj
APA 6th Edition
McKean, D.C. (1988). Interpreting the eH Stretching Region, Through Infrared Partial Deuteration Studies. Croatica Chemica Acta, 61 (2), 447-461. Preuzeto s https://hrcak.srce.hr/175923
MLA 8th Edition
McKean, D. C.. "Interpreting the eH Stretching Region, Through Infrared Partial Deuteration Studies." Croatica Chemica Acta, vol. 61, br. 2, 1988, str. 447-461. https://hrcak.srce.hr/175923. Citirano 28.02.2021.
Chicago 17th Edition
McKean, D. C.. "Interpreting the eH Stretching Region, Through Infrared Partial Deuteration Studies." Croatica Chemica Acta 61, br. 2 (1988): 447-461. https://hrcak.srce.hr/175923
Harvard
McKean, D.C. (1988). 'Interpreting the eH Stretching Region, Through Infrared Partial Deuteration Studies', Croatica Chemica Acta, 61(2), str. 447-461. Preuzeto s: https://hrcak.srce.hr/175923 (Datum pristupa: 28.02.2021.)
Vancouver
McKean DC. Interpreting the eH Stretching Region, Through Infrared Partial Deuteration Studies. Croatica Chemica Acta [Internet]. 1988 [pristupljeno 28.02.2021.];61(2):447-461. Dostupno na: https://hrcak.srce.hr/175923
IEEE
D.C. McKean, "Interpreting the eH Stretching Region, Through Infrared Partial Deuteration Studies", Croatica Chemica Acta, vol.61, br. 2, str. 447-461, 1988. [Online]. Dostupno na: https://hrcak.srce.hr/175923. [Citirano: 28.02.2021.]

Sažetak
Information derived from a study of 'isolated' CH stretching
frequencies, measured in partially deuterated organic and organemetallic compounds, is reviewed. This includes CH bond lengths and dissociation energies, and HCH angles in methyl groups, Excellent agreement is found between CH bond length differences predicted from VCH's values and those calculated by ab initio methods. V'sCH data also agree with the results of high overtone, local mode studies in distinguishing differences in CH bond strengths. The former however are based on spectra which are easier to assign
to specific bonds. They also enable one to understand the spectra
of normal, undeuterated molecules in the CH stretching region,
through 'energy factored force field' calculations. Reference is made to situations involvlng free internal rotation of methyl groups, and to studies of other 'isolated' MH bonds (M = N, Si, Ge, Sn).

Hrčak ID: 175923

URI
https://hrcak.srce.hr/175923

Posjeta: 158 *