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Preparation of Chiral Diphenylphosphines from D-Glucose and Enantioselective Hydrogenation with Their Rh(l) Complexes

Ivan Habuš ; Rudjer Bošković Institute, Department of Organic Chemistry and Biochemistry, P.O.B. 1016, 41001 Zagreb, Yugoslavia
ZLata Raza ; Rudjer Bošković Institute, Department of Organic Chemistry and Biochemistry, P.O.B. 1016, 41001 Zagreb, Yugoslavia
Vitomir Šunjić ; Rudjer Bošković Institute, Department of Organic Chemistry and Biochemistry, P.O.B. 1016, 41001 Zagreb, Yugoslavia

Puni tekst: engleski, pdf (4 MB) str. 857-866 preuzimanja: 72* citiraj
APA 6th Edition
Habuš, I., Raza, Z. i Šunjić, V. (1988). Preparation of Chiral Diphenylphosphines from D-Glucose and Enantioselective Hydrogenation with Their Rh(l) Complexes. Croatica Chemica Acta, 61 (4), 857-866. Preuzeto s https://hrcak.srce.hr/176017
MLA 8th Edition
Habuš, Ivan, et al. "Preparation of Chiral Diphenylphosphines from D-Glucose and Enantioselective Hydrogenation with Their Rh(l) Complexes." Croatica Chemica Acta, vol. 61, br. 4, 1988, str. 857-866. https://hrcak.srce.hr/176017. Citirano 25.02.2021.
Chicago 17th Edition
Habuš, Ivan, ZLata Raza i Vitomir Šunjić. "Preparation of Chiral Diphenylphosphines from D-Glucose and Enantioselective Hydrogenation with Their Rh(l) Complexes." Croatica Chemica Acta 61, br. 4 (1988): 857-866. https://hrcak.srce.hr/176017
Harvard
Habuš, I., Raza, Z., i Šunjić, V. (1988). 'Preparation of Chiral Diphenylphosphines from D-Glucose and Enantioselective Hydrogenation with Their Rh(l) Complexes', Croatica Chemica Acta, 61(4), str. 857-866. Preuzeto s: https://hrcak.srce.hr/176017 (Datum pristupa: 25.02.2021.)
Vancouver
Habuš I, Raza Z, Šunjić V. Preparation of Chiral Diphenylphosphines from D-Glucose and Enantioselective Hydrogenation with Their Rh(l) Complexes. Croatica Chemica Acta [Internet]. 1988 [pristupljeno 25.02.2021.];61(4):857-866. Dostupno na: https://hrcak.srce.hr/176017
IEEE
I. Habuš, Z. Raza i V. Šunjić, "Preparation of Chiral Diphenylphosphines from D-Glucose and Enantioselective Hydrogenation with Their Rh(l) Complexes", Croatica Chemica Acta, vol.61, br. 4, str. 857-866, 1988. [Online]. Dostupno na: https://hrcak.srce.hr/176017. [Citirano: 25.02.2021.]

Sažetak
(2R,3S)-2-Methylsulfonyloxymeihyl-3-methylsulfonyloxy-tetrahydropyran (4), derived from n-glucose, is diphenylphosphinated to (2R,3R)-2-diphenylphosphinomethyl-3-diphenylphosphino-tetrahydropyran (7), which is formed as aminor product. Compound 8 is the predominant product, formed on 3,4-elimination. Preparation
and characterization of the rhodium(I) complexes 10-12 is described.
Complex 10 of bidentate Iigand 7 exhibits in hydrogenation of Z-a-N-acetylaminocinnamic acid enantioselectivity comparable to that obtained with rhodium(I) complex of (-)-DIOP (-70010e. e.). Saturated monophosphine, (2S)-2-diphenylphosphinomethyl-tetrahydropyran (9) affords mixed rhodium(I) complex (11, 12), which exhibits low enantioselectivity.

Hrčak ID: 176017

URI
https://hrcak.srce.hr/176017

Posjeta: 167 *