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Circular Dichroism of Optically Active 1,2-Disubstituted 1,2-Diphenyl Ethanes. Part III. Compounds with a COOR-group at Benzylic C

Nikolina Berova ; Institute of Organic Chemistry, Bulgarian Academy of Sciences, Sofia (Bulgaria)
Bogdan Kurtev ; Institute of Organic Chemistry, Bulgarian Academy of Sciences, Sofia (Bulgaria)
Gunther Snatzke ; Lehrstuhl fur Strukturchemie, Ruhruniversitat Bochum (FRG)

Puni tekst: engleski, pdf (8 MB) str. 243-262 preuzimanja: 136* citiraj
APA 6th Edition
Berova, N., Kurtev, B. i Snatzke, G. (1987). Circular Dichroism of Optically Active 1,2-Disubstituted 1,2-Diphenyl Ethanes. Part III. Compounds with a COOR-group at Benzylic C. Croatica Chemica Acta, 60 (2), 243-262. Preuzeto s https://hrcak.srce.hr/176352
MLA 8th Edition
Berova, Nikolina, et al. "Circular Dichroism of Optically Active 1,2-Disubstituted 1,2-Diphenyl Ethanes. Part III. Compounds with a COOR-group at Benzylic C." Croatica Chemica Acta, vol. 60, br. 2, 1987, str. 243-262. https://hrcak.srce.hr/176352. Citirano 06.03.2021.
Chicago 17th Edition
Berova, Nikolina, Bogdan Kurtev i Gunther Snatzke. "Circular Dichroism of Optically Active 1,2-Disubstituted 1,2-Diphenyl Ethanes. Part III. Compounds with a COOR-group at Benzylic C." Croatica Chemica Acta 60, br. 2 (1987): 243-262. https://hrcak.srce.hr/176352
Harvard
Berova, N., Kurtev, B., i Snatzke, G. (1987). 'Circular Dichroism of Optically Active 1,2-Disubstituted 1,2-Diphenyl Ethanes. Part III. Compounds with a COOR-group at Benzylic C', Croatica Chemica Acta, 60(2), str. 243-262. Preuzeto s: https://hrcak.srce.hr/176352 (Datum pristupa: 06.03.2021.)
Vancouver
Berova N, Kurtev B, Snatzke G. Circular Dichroism of Optically Active 1,2-Disubstituted 1,2-Diphenyl Ethanes. Part III. Compounds with a COOR-group at Benzylic C. Croatica Chemica Acta [Internet]. 1987 [pristupljeno 06.03.2021.];60(2):243-262. Dostupno na: https://hrcak.srce.hr/176352
IEEE
N. Berova, B. Kurtev i G. Snatzke, "Circular Dichroism of Optically Active 1,2-Disubstituted 1,2-Diphenyl Ethanes. Part III. Compounds with a COOR-group at Benzylic C", Croatica Chemica Acta, vol.60, br. 2, str. 243-262, 1987. [Online]. Dostupno na: https://hrcak.srce.hr/176352. [Citirano: 06.03.2021.]

Sažetak
Optically active 1,2-diphenyl ethanes containing a COOR - group on one of the benzylic C-atoms give a relatively strong n ~]1;* - Cotton effect around 225 nm in addition to those found for 1,2-diphenyl ethanes lacking this type of substitution, and for which the usual regularities hold which were described in our previous paper. Its sign follows the rule known for such optically active phenyl acetic acid derivatives. This additional band is often detectable only from a broader halfband width of the Cotton effect present in this wavelength range, can, however, clearly be seen when the CD-curve of the analogue containing the moiety CH20H instead of the COOR-group is subtracted from the original CD-curve. Effect of the solvent (isooctane vs. acetonitrile) and temperature was studied, as well as the influence of salt formation on the position and fine structure of some Cotton effects.

Hrčak ID: 176352

URI
https://hrcak.srce.hr/176352

Posjeta: 222 *