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An Analysis of the Shape of the Coordination Polyhedron of Pentacoordinated Copper(II) Chelates with N-Alkylated Amino Acids

Nenad Raos ; Laboratory for Analytical and Physical Chemistry, Institute for Medical Research and Occupational Health, Zagreb, Croatia

Puni tekst: engleski, pdf (7 MB) str. 1189-1200 preuzimanja: 112* citiraj
APA 6th Edition
Raos, N. (1996). An Analysis of the Shape of the Coordination Polyhedron of Pentacoordinated Copper(II) Chelates with N-Alkylated Amino Acids. Croatica Chemica Acta, 69 (3), 1189-1200. Preuzeto s https://hrcak.srce.hr/177138
MLA 8th Edition
Raos, Nenad. "An Analysis of the Shape of the Coordination Polyhedron of Pentacoordinated Copper(II) Chelates with N-Alkylated Amino Acids." Croatica Chemica Acta, vol. 69, br. 3, 1996, str. 1189-1200. https://hrcak.srce.hr/177138. Citirano 21.06.2021.
Chicago 17th Edition
Raos, Nenad. "An Analysis of the Shape of the Coordination Polyhedron of Pentacoordinated Copper(II) Chelates with N-Alkylated Amino Acids." Croatica Chemica Acta 69, br. 3 (1996): 1189-1200. https://hrcak.srce.hr/177138
Harvard
Raos, N. (1996). 'An Analysis of the Shape of the Coordination Polyhedron of Pentacoordinated Copper(II) Chelates with N-Alkylated Amino Acids', Croatica Chemica Acta, 69(3), str. 1189-1200. Preuzeto s: https://hrcak.srce.hr/177138 (Datum pristupa: 21.06.2021.)
Vancouver
Raos N. An Analysis of the Shape of the Coordination Polyhedron of Pentacoordinated Copper(II) Chelates with N-Alkylated Amino Acids. Croatica Chemica Acta [Internet]. 1996 [pristupljeno 21.06.2021.];69(3):1189-1200. Dostupno na: https://hrcak.srce.hr/177138
IEEE
N. Raos, "An Analysis of the Shape of the Coordination Polyhedron of Pentacoordinated Copper(II) Chelates with N-Alkylated Amino Acids", Croatica Chemica Acta, vol.69, br. 3, str. 1189-1200, 1996. [Online]. Dostupno na: https://hrcak.srce.hr/177138. [Citirano: 21.06.2021.]

Sažetak
An analysis of eight pentacoordinated (aqua) copper(II) chelates
with N-alkylated amino acids revealed that they could be separated
in two group s with respect to the shape of their coordination
polyhedra. Group I, consisting of N,N-dimethylated derivatives,
can be described as distorted square pyramids with a pseudo C4v
symmetry. Group II, consisting of other N-alkylated and N,N-dialkylated derivatives, can be described as square pyramids distorted towards the trigonal pyramid along the axis O-Cu-O' = 180°. The apical bond length (Cu-OH2) correlates extremely well on the NCu- N' angle tr = 0.9996) for the group I molecules and sub stantially less well for group II (r = 0.954). Multiple regression of experimental apical lengths on the N-Cu-N' angle and the absolute
difference IN-Cu-N' - O-Cu-O'I yields IRI= 0.981 for N = 8. By applying the different measures of distortion of the copper(II) coordination polyhedron, it was possible to predict the apical bond length from the structures obtained by molecular mechanics calculations with the minimum value for the root-mean-square deviation between experiment and the ory 0.083 A (group I), 0.032 A (group II) and 0.068 A (both groups).

Hrčak ID: 177138

URI
https://hrcak.srce.hr/177138

Posjeta: 227 *