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https://doi.org/10.5562/cca3241

Effect of Methoxy Substitution on Supramolecular Arrangement of Borondifluorides of 2'-Hydroxy Chalcones and their Solid-State NIR Fluorescence

Anthony D'Aléo ; Aix Marseille Univ, CNRS, CINaM UMR 7325, Campus de Luminy, Case 913, 13288 Marseille, France
Elena Zaborova ; Aix Marseille Univ, CNRS, CINaM UMR 7325, Campus de Luminy, Case 913, 13288 Marseille, France
Frédéric Fages orcid id orcid.org/0000-0003-2013-0710 ; Aix Marseille Univ, CNRS, CINaM UMR 7325, Campus de Luminy, Case 913, 13288 Marseille, France


Puni tekst: engleski pdf 5.103 Kb

str. 583-588

preuzimanja: 692

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Sažetak

This work describes the borondifluoride complexes of 2'-hydroxychalcone derivatives, 2 and 3, differently substituted with methoxy groups. Their optical study in dichloromethane reveals similar UV-vis absorption and fluorescence emission features in the visible spectral region that are close to those of the parent compound 1. While fluorescence quantum yields Φf are very low in solution, they are higher in the solid state, showing that aggregation-induced enhanced emission occurs. Remarkably, the solid-state emission spectra are strongly red-shifted reaching the near infrared (NIR) spectral range. Molecular structures of 2 and 3 were determined by single crystal X-ray diffraction. The data show the occurrence of tightly packed arrangements that favor strong π-π overlap between neighboring molecules. Such situation allows the generation of promising NIR emitting materials, such as compound 3 emitting at 784 nm with Φf = 0.07 that stands as one of the best NIR solid-state organic emitters.

This work is licensed under a Creative Commons Attribution 4.0 International License.

Ključne riječi

fluorescence; solid state; near infrared; boron complexes; chalcones

Hrčak ID:

193868

URI

https://hrcak.srce.hr/193868

Datum izdavanja:

29.12.2017.

Posjeta: 1.155 *