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The Problem of Enantiomers: Support for a New Interpretation of Quantum Mechanics

Andre Julg ; Laboratoire de Chimie Theorique, Universite de Provence, Place Victor Hugo, 13331 Marseille Cedex 3, France

Puni tekst: engleski, pdf (5 MB) str. 1497-1507 preuzimanja: 62* citiraj
APA 6th Edition
Julg, A. (1984). The Problem of Enantiomers: Support for a New Interpretation of Quantum Mechanics. Croatica Chemica Acta, 57 (6), 1497-1507. Preuzeto s https://hrcak.srce.hr/194040
MLA 8th Edition
Julg, Andre. "The Problem of Enantiomers: Support for a New Interpretation of Quantum Mechanics." Croatica Chemica Acta, vol. 57, br. 6, 1984, str. 1497-1507. https://hrcak.srce.hr/194040. Citirano 08.03.2021.
Chicago 17th Edition
Julg, Andre. "The Problem of Enantiomers: Support for a New Interpretation of Quantum Mechanics." Croatica Chemica Acta 57, br. 6 (1984): 1497-1507. https://hrcak.srce.hr/194040
Harvard
Julg, A. (1984). 'The Problem of Enantiomers: Support for a New Interpretation of Quantum Mechanics', Croatica Chemica Acta, 57(6), str. 1497-1507. Preuzeto s: https://hrcak.srce.hr/194040 (Datum pristupa: 08.03.2021.)
Vancouver
Julg A. The Problem of Enantiomers: Support for a New Interpretation of Quantum Mechanics. Croatica Chemica Acta [Internet]. 1984 [pristupljeno 08.03.2021.];57(6):1497-1507. Dostupno na: https://hrcak.srce.hr/194040
IEEE
A. Julg, "The Problem of Enantiomers: Support for a New Interpretation of Quantum Mechanics", Croatica Chemica Acta, vol.57, br. 6, str. 1497-1507, 1984. [Online]. Dostupno na: https://hrcak.srce.hr/194040. [Citirano: 08.03.2021.]

Sažetak
The problem of enantiomers is a typical case of the difficulties
which quantum mechanics encounters concerning the interpretation
of molecular structure. Classically, each enantiomer has to be·
considered as a different molecule. The transforma1ion of one form
to the other is interpreted as resulting from a more or less fast
oscillation between the two forms. Within strict quantum formalism
the two enantiomers are described by the same wave-function,
corresponding to a rotatory power equal to zero. The oscillation
between the two forms is artificially obtained in considering ct
non-stationary state, different from the ground state. The difference
in behavior between amines (non dedoublable) and arsines (dedoublable) is impossible to explain. A solution is proposed within
a new interpretation of quantum mechanics, according to which
quantum formalism would give the average value of various properties
for a sufficiently long time.

Hrčak ID: 194040

URI
https://hrcak.srce.hr/194040

Posjeta: 126 *