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A Folded Conformation of 1,4,8,11-Tetrathiacyclotetradecane in its Mercury Compound: l,4,8,11-Tetrathiacyclotetradecanedipicratomercury( II) Heminitromethane, [Hg(C10H20S4)· (C6H2N307)2] · 1/2CH3N02

Marija Herceg ; Rudjer Boskovic Institute, 41001 Zagreb, Yugoslavia
Boris Matković ; Rudjer Boskovic Institute, 41001 Zagreb, Yugoslavia
Drenka Sevdić ; Rudjer Boskovic Institute, 41001 Zagreb, Yugoslavia
Dubravka Matković-Čalogović ; Faculty of Science, University of Zagreb, 41001 Zagreb, Yugoslavia
Ante Nagl ; Faculty of Science, University of Zagreb, 41001 Zagreb, Yugoslavia

Puni tekst: engleski, pdf (13 MB) str. 609-619 preuzimanja: 52* citiraj
APA 6th Edition
Herceg, M., Matković, B., Sevdić, D., Matković-Čalogović, D. i Nagl, A. (1984). A Folded Conformation of 1,4,8,11-Tetrathiacyclotetradecane in its Mercury Compound: l,4,8,11-Tetrathiacyclotetradecanedipicratomercury( II) Heminitromethane, [Hg(C10H20S4)· (C6H2N307)2] · 1/2CH3N02. Croatica Chemica Acta, 57 (4), 609-619. Preuzeto s https://hrcak.srce.hr/194129
MLA 8th Edition
Herceg, Marija, et al. "A Folded Conformation of 1,4,8,11-Tetrathiacyclotetradecane in its Mercury Compound: l,4,8,11-Tetrathiacyclotetradecanedipicratomercury( II) Heminitromethane, [Hg(C10H20S4)· (C6H2N307)2] · 1/2CH3N02." Croatica Chemica Acta, vol. 57, br. 4, 1984, str. 609-619. https://hrcak.srce.hr/194129. Citirano 31.03.2020.
Chicago 17th Edition
Herceg, Marija, Boris Matković, Drenka Sevdić, Dubravka Matković-Čalogović i Ante Nagl. "A Folded Conformation of 1,4,8,11-Tetrathiacyclotetradecane in its Mercury Compound: l,4,8,11-Tetrathiacyclotetradecanedipicratomercury( II) Heminitromethane, [Hg(C10H20S4)· (C6H2N307)2] · 1/2CH3N02." Croatica Chemica Acta 57, br. 4 (1984): 609-619. https://hrcak.srce.hr/194129
Harvard
Herceg, M., et al. (1984). 'A Folded Conformation of 1,4,8,11-Tetrathiacyclotetradecane in its Mercury Compound: l,4,8,11-Tetrathiacyclotetradecanedipicratomercury( II) Heminitromethane, [Hg(C10H20S4)· (C6H2N307)2] · 1/2CH3N02', Croatica Chemica Acta, 57(4), str. 609-619. Preuzeto s: https://hrcak.srce.hr/194129 (Datum pristupa: 31.03.2020.)
Vancouver
Herceg M, Matković B, Sevdić D, Matković-Čalogović D, Nagl A. A Folded Conformation of 1,4,8,11-Tetrathiacyclotetradecane in its Mercury Compound: l,4,8,11-Tetrathiacyclotetradecanedipicratomercury( II) Heminitromethane, [Hg(C10H20S4)· (C6H2N307)2] · 1/2CH3N02. Croatica Chemica Acta [Internet]. 1984 [pristupljeno 31.03.2020.];57(4):609-619. Dostupno na: https://hrcak.srce.hr/194129
IEEE
M. Herceg, B. Matković, D. Sevdić, D. Matković-Čalogović i A. Nagl, "A Folded Conformation of 1,4,8,11-Tetrathiacyclotetradecane in its Mercury Compound: l,4,8,11-Tetrathiacyclotetradecanedipicratomercury( II) Heminitromethane, [Hg(C10H20S4)· (C6H2N307)2] · 1/2CH3N02", Croatica Chemica Acta, vol.57, br. 4, str. 609-619, 1984. [Online]. Dostupno na: https://hrcak.srce.hr/194129. [Citirano: 31.03.2020.]

Sažetak
The crystals of 1,4,8,11-tetrathiacyclotetradecanedipicratomercury(
II) heminitromethane, [Hg(C10H20S4) · (CsH2Ns01h] · 1/2CHsN02,
are triclinic, spcrce group Pl with a = 1.2794(6), b = 1.3108(5), c =
= 1.0090(3) nm, a= 92.85(3) 0
, fJ = 107.67(3)0
, y = 94.54(4) 0
, V = 1.60236
nm3, and Z = 2. The structure was solved by the heavy atom
method and refined by the least-squares method to R = 0.030 for
the 7321 unique reflections. It consists of discrete, well separated
molecules. Coordination of the mercury atom is a distorted octahedron
with four sulfur atoms (Hg-S distances are 245.8(1),
251.9(1), 262 .. 9(2), and 305.0(2) pm) from the macrocycle and two
oxygen moms (Hg-0 distances are 253.1(3) and 255.8(3) pm) from
the two picrates. The macrocycle is folded so that three sulfur
atoms with short Hg-S bonds are in an equatorial and the fourth
in an apical position. The conformation of the coordinated macrocycle
is compared to the conformation of cyclotetradecane at 116 K
and to the conformation of the free crysta-lline macrocycle.

Hrčak ID: 194129

URI
https://hrcak.srce.hr/194129

Posjeta: 86 *