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An Investigation of the Acceptor Properties of Some Organomercurials by Molecular Weight Measurements and X-ray Photoelectron Spectroscopy

Glen B. Deacon ; Chemistry Department, Monash University, Clayton, Vic. 3168, Australia
Anna Florenti ; Chemistry Department, Monash University, Clayton, Vic. 3168, Australia
Marshall Hughes ; Chemistry Department, University of Tasmania, P.O. Box 252C, Hobart, Tas. 7001, Australia
Frank P. Larkins ; Chemistry Department, University of Tasmania, P.O. Box 252C, Hobart, Tas. 7001, Australia

Puni tekst: engleski, pdf (11 MB) str. 757-764 preuzimanja: 45* citiraj
APA 6th Edition
Deacon, G.B., Florenti, A., Hughes, M. i Larkins, F.P. (1984). An Investigation of the Acceptor Properties of Some Organomercurials by Molecular Weight Measurements and X-ray Photoelectron Spectroscopy. Croatica Chemica Acta, 57 (4), 757-764. Preuzeto s https://hrcak.srce.hr/194145
MLA 8th Edition
Deacon, Glen B., et al. "An Investigation of the Acceptor Properties of Some Organomercurials by Molecular Weight Measurements and X-ray Photoelectron Spectroscopy." Croatica Chemica Acta, vol. 57, br. 4, 1984, str. 757-764. https://hrcak.srce.hr/194145. Citirano 08.04.2020.
Chicago 17th Edition
Deacon, Glen B., Anna Florenti, Marshall Hughes i Frank P. Larkins. "An Investigation of the Acceptor Properties of Some Organomercurials by Molecular Weight Measurements and X-ray Photoelectron Spectroscopy." Croatica Chemica Acta 57, br. 4 (1984): 757-764. https://hrcak.srce.hr/194145
Harvard
Deacon, G.B., et al. (1984). 'An Investigation of the Acceptor Properties of Some Organomercurials by Molecular Weight Measurements and X-ray Photoelectron Spectroscopy', Croatica Chemica Acta, 57(4), str. 757-764. Preuzeto s: https://hrcak.srce.hr/194145 (Datum pristupa: 08.04.2020.)
Vancouver
Deacon GB, Florenti A, Hughes M, Larkins FP. An Investigation of the Acceptor Properties of Some Organomercurials by Molecular Weight Measurements and X-ray Photoelectron Spectroscopy. Croatica Chemica Acta [Internet]. 1984 [pristupljeno 08.04.2020.];57(4):757-764. Dostupno na: https://hrcak.srce.hr/194145
IEEE
G.B. Deacon, A. Florenti, M. Hughes i F.P. Larkins, "An Investigation of the Acceptor Properties of Some Organomercurials by Molecular Weight Measurements and X-ray Photoelectron Spectroscopy", Croatica Chemica Acta, vol.57, br. 4, str. 757-764, 1984. [Online]. Dostupno na: https://hrcak.srce.hr/194145. [Citirano: 08.04.2020.]

Sažetak
Stability constants from molecular weigth measurements for
the complexes R2Hgbpy (bpy = 2,2'-bipyridyl) in carbon tetrachloride
and benzene at 25 °C decrease in the order R = CaF5 >
> p-HC6F4 = p-MeOC6F4 2': o-HC5F4, and for R2HgOPPha, in the
order R = o-HC6F4 > C5F5 > p-HC5F4 = p-MeOC5F4 with higher
values in the former solvent. The unexpectedly greater stability of
(o-HC5F4)2HgOPPha than (C5F5)2HgOPPha has been related to the
structures of the parent mercurials. X-ray photoelectron spectroscopy
shows that the acceptor properties of mercury compounds
decrease in the order HgCl2 > (C5F5)2Hg = (p-HC5F4)2Hg = (o-
HC0F4)2Hg > (p-MeOCoF4)2Hg > (C5Cls)2Hg 2': Ph2Hg > Hg0• A similar study of RHgX compounds suggests that there is reasonable
additivity of the electrophilic effects of different R and X groups
on the mercury 4f binding energy.

Hrčak ID: 194145

URI
https://hrcak.srce.hr/194145

Posjeta: 76 *