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Pregledni rad
Quantitative IR Spectroscopy of H-Bonds: Intensities of v, Bands
Yves Marechal
; Centre d'Etudes Nucleaires de Grenoble, Departement de Recherche Fondamentale, Section de Resonance Magnetique, 85 X - 38041 Grenoble Cedex, France
| Puni tekst: engleski, pdf (6 MB) | str. 129-132 | citiraj | |
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APA 6th Edition Marechal, Y. (1982). Quantitative IR Spectroscopy of H-Bonds: Intensities of v, Bands. Croatica Chemica Acta, 55 (1-2), 129-132. Preuzeto s https://hrcak.srce.hr/194286 MLA 8th Edition Marechal, Yves. "Quantitative IR Spectroscopy of H-Bonds: Intensities of v, Bands." Croatica Chemica Acta, vol. 55, br. 1-2, 1982, str. 129-132. https://hrcak.srce.hr/194286. Citirano 06.03.2021. Chicago 17th Edition Marechal, Yves. "Quantitative IR Spectroscopy of H-Bonds: Intensities of v, Bands." Croatica Chemica Acta 55, br. 1-2 (1982): 129-132. https://hrcak.srce.hr/194286 Harvard Marechal, Y. (1982). 'Quantitative IR Spectroscopy of H-Bonds: Intensities of v, Bands', Croatica Chemica Acta, 55(1-2), str. 129-132. Preuzeto s: https://hrcak.srce.hr/194286 (Datum pristupa: 06.03.2021.) Vancouver Marechal Y. Quantitative IR Spectroscopy of H-Bonds: Intensities of v, Bands. Croatica Chemica Acta [Internet]. 1982 [pristupljeno 06.03.2021.];55(1-2):129-132. Dostupno na: https://hrcak.srce.hr/194286 IEEE Y. Marechal, "Quantitative IR Spectroscopy of H-Bonds: Intensities of v, Bands", Croatica Chemica Acta, vol.55, br. 1-2, str. 129-132, 1982. [Online]. Dostupno na: https://hrcak.srce.hr/194286. [Citirano: 06.03.2021.] |
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Sažetak
In this article we stress the interest of performing precise
measurements concerning the IR spectra of H-bonds, as this has
been initiated under the impulsion of Professor Hadzi. We concentrate
on the few measurements which have been made of the
intensities of the ''s bands (X-H· · ·Y), which are highly cha-·
racteristic of H-bonds. These intensities have shown some intriguing
features: upon deuteration of the H-bond they often decrease
far more than expected. This is particularly marked for the
H-bonded cyclic dimers of carboxylic acids. It can be explained
by electrical anharmonicity but can also be a manifestation of
some cooperative effect between the two H-bonds of these dimers.
Hrčak ID: 194286
URI
https://hrcak.srce.hr/194286
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