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Mode Coupling in Molecular Complexes

Nikolai D. Sokolov ; Institute of Chemical Physics, Academy of Sciences of the USSR, Ul. Kosygina 4, 117334, Moscow V-334, USSR

Puni tekst: engleski, pdf (9 MB) str. 223-231 preuzimanja: 52* citiraj
APA 6th Edition
Sokolov, N.D. (1982). Mode Coupling in Molecular Complexes. Croatica Chemica Acta, 55 (1-2), 223-231. Preuzeto s https://hrcak.srce.hr/194294
MLA 8th Edition
Sokolov, Nikolai D.. "Mode Coupling in Molecular Complexes." Croatica Chemica Acta, vol. 55, br. 1-2, 1982, str. 223-231. https://hrcak.srce.hr/194294. Citirano 04.03.2021.
Chicago 17th Edition
Sokolov, Nikolai D.. "Mode Coupling in Molecular Complexes." Croatica Chemica Acta 55, br. 1-2 (1982): 223-231. https://hrcak.srce.hr/194294
Harvard
Sokolov, N.D. (1982). 'Mode Coupling in Molecular Complexes', Croatica Chemica Acta, 55(1-2), str. 223-231. Preuzeto s: https://hrcak.srce.hr/194294 (Datum pristupa: 04.03.2021.)
Vancouver
Sokolov ND. Mode Coupling in Molecular Complexes. Croatica Chemica Acta [Internet]. 1982 [pristupljeno 04.03.2021.];55(1-2):223-231. Dostupno na: https://hrcak.srce.hr/194294
IEEE
N.D. Sokolov, "Mode Coupling in Molecular Complexes", Croatica Chemica Acta, vol.55, br. 1-2, str. 223-231, 1982. [Online]. Dostupno na: https://hrcak.srce.hr/194294. [Citirano: 04.03.2021.]

Sažetak
Different dynamical properties of the hydrogen bond and
charge transfer complexes are described from the same point of
view. An introduction of a coupling parameter responsible for the
A-Z and A· · · B mode interaction in the system A-Z · · · B (Z is
the hydrogen or halogen atom) permits to interpret quantitatively
some empirical findings and regularities. They are the A-Z bond
length increasing on complexing, the A-Z stretching band shift
towards lower frequencies and its linear dependence on the A-Z
bond lengthening, the isotopic effects for the A· · · B and A-H bond
lengths and for the A-H stretching frequency, the A-Z vibrational
band broadening on complexing in the liquid phase and a
dependence between the band halfwidth and the frequency shift.
Some relations containing no fitting parameters are established
in a good agreement with experiment.

Hrčak ID: 194294

URI
https://hrcak.srce.hr/194294

Posjeta: 106 *