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Vibrational Spectroscopy of Compounds with Very Short Hydrogen Bonds. The Aqueous Bisformate Ion. Comparison with Two Solid Salts, and Some Comments on Broad OH Absorption Continua

Ernest Spinner ; Medical Chemistry Group, Australian National University, Canberra, A. C. T. 2601, Australia

Puni tekst: engleski, pdf (28 MB) str. 249-269 preuzimanja: 48* citiraj
APA 6th Edition
Spinner, E. (1982). Vibrational Spectroscopy of Compounds with Very Short Hydrogen Bonds. The Aqueous Bisformate Ion. Comparison with Two Solid Salts, and Some Comments on Broad OH Absorption Continua. Croatica Chemica Acta, 55 (1-2), 249-269. Preuzeto s https://hrcak.srce.hr/194296
MLA 8th Edition
Spinner, Ernest. "Vibrational Spectroscopy of Compounds with Very Short Hydrogen Bonds. The Aqueous Bisformate Ion. Comparison with Two Solid Salts, and Some Comments on Broad OH Absorption Continua." Croatica Chemica Acta, vol. 55, br. 1-2, 1982, str. 249-269. https://hrcak.srce.hr/194296. Citirano 05.03.2021.
Chicago 17th Edition
Spinner, Ernest. "Vibrational Spectroscopy of Compounds with Very Short Hydrogen Bonds. The Aqueous Bisformate Ion. Comparison with Two Solid Salts, and Some Comments on Broad OH Absorption Continua." Croatica Chemica Acta 55, br. 1-2 (1982): 249-269. https://hrcak.srce.hr/194296
Harvard
Spinner, E. (1982). 'Vibrational Spectroscopy of Compounds with Very Short Hydrogen Bonds. The Aqueous Bisformate Ion. Comparison with Two Solid Salts, and Some Comments on Broad OH Absorption Continua', Croatica Chemica Acta, 55(1-2), str. 249-269. Preuzeto s: https://hrcak.srce.hr/194296 (Datum pristupa: 05.03.2021.)
Vancouver
Spinner E. Vibrational Spectroscopy of Compounds with Very Short Hydrogen Bonds. The Aqueous Bisformate Ion. Comparison with Two Solid Salts, and Some Comments on Broad OH Absorption Continua. Croatica Chemica Acta [Internet]. 1982 [pristupljeno 05.03.2021.];55(1-2):249-269. Dostupno na: https://hrcak.srce.hr/194296
IEEE
E. Spinner, "Vibrational Spectroscopy of Compounds with Very Short Hydrogen Bonds. The Aqueous Bisformate Ion. Comparison with Two Solid Salts, and Some Comments on Broad OH Absorption Continua", Croatica Chemica Acta, vol.55, br. 1-2, str. 249-269, 1982. [Online]. Dostupno na: https://hrcak.srce.hr/194296. [Citirano: 05.03.2021.]

Sažetak
The infrared and Raman spectra of aqueous bisformate ions
(HC02)2ff, (HC02)2D-, (DC02)ff, (DC02)2D-, and of the isotopic
mixture (HC02) (DC02)H- are reported. For hydroxyl stretching
YOH = YOD = 1400 cm-1 (cf. ca. 1100 cm-1 in the solid Na+ and ca.
1400 cm-1 in the K+ salt). All the bands expected for a formate ion
moiety and most of those expected for a formic acid moiety appear
in both the infrared and the Raman spectrum (as for the solid
Na+ salt). Essentially unmodified formate ion is complexed with
appreciably modified formic acid and the complex does not possess
the centrosymmetric C21i structure predicted for it by a recent
ab initio molecular orbitals calculation, nor a centrosymmetric
OHO bond.

Hrčak ID: 194296

URI
https://hrcak.srce.hr/194296

Posjeta: 94 *