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Transition Metal Chemistry of Oxime-Containing Ligands, Part XIV. Iron(II) Complexes of syn-Phenyl-2-pyridylketoxime and syn-Methy 1-2-pyridylketoxime

Madan Mohan ; Department of Chemistry, N.R.E.C College, Khurja-203131 (U.P.) India
Bhikari D. Paramhans ; Department of Chemistry, N.R.E.C College, Khurja-203131 (U.P.) India

Sažetak

Iron(II) complexes of the type [Fe(HL)2X2] (where HL =
syn-phenyl-2-pyridylketoxime (Hppk) or syn-methyl-2-pyridylketoxime
(Hmpk) and X = c1-, Br-, I-, Ncs- or NCse-) were synthesized
and characterized by elemental analysis, molar conductance,
molecular weight determination, X-ray powder diffraction
patterns, magnetic susceptibility, Mossbauer, reflectance and IR
spectral measurements. On the basis of these physical properties
a halo-bridged dimeric cis- octahedral structure is suggested for
the iron(II) halo complexes, whereas the remaining complexes
appear to be monomeric with a cis- octahedral structur e.

Ključne riječi

Hrčak ID:

194334

URI

https://hrcak.srce.hr/194334

Datum izdavanja:

20.7.1981.

Posjeta: 498 *