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MIND0/3 Study of the 'Thermal Rearrangements of Bicyclobutanylidene

See-Wing Chiu ; Department of Chemistry, The Chinese University of Hong Kong Shatin, N. T., Hong Kong
Wai-Kee Li ; Department of Chemistry, The Chinese University of Hong Kong Shatin, N. T., Hong Kong

Sažetak

It is found that path (i), which is concerted and stereospecific, is
favored both thermodynamically and kinetically, in agreement
with exp~'rimental results. In addition, paths (ii) and (iii) are found
to be competitive with each other and both are highly energetic
due to steric effects, with activation energy being about 50 kcal/mo!.

Ključne riječi

Hrčak ID:

194335

URI

https://hrcak.srce.hr/194335

Datum izdavanja:

20.7.1981.

Posjeta: 367 *