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Metal Complexes of Carbazic Acids IV. Chromium(III) Complexes of N-Substituted Carbazic Acids

A. K. Srivastava ; Department of Chemistry, Meerut College, Meerut, India

Puni tekst: engleski, pdf (3 MB) str. 293-298 preuzimanja: 61* citiraj
APA 6th Edition
Srivastava, A.K. (1979). Metal Complexes of Carbazic Acids IV. Chromium(III) Complexes of N-Substituted Carbazic Acids. Croatica Chemica Acta, 52 (3), 293-298. Preuzeto s https://hrcak.srce.hr/195889
MLA 8th Edition
Srivastava, A. K.. "Metal Complexes of Carbazic Acids IV. Chromium(III) Complexes of N-Substituted Carbazic Acids." Croatica Chemica Acta, vol. 52, br. 3, 1979, str. 293-298. https://hrcak.srce.hr/195889. Citirano 05.03.2021.
Chicago 17th Edition
Srivastava, A. K.. "Metal Complexes of Carbazic Acids IV. Chromium(III) Complexes of N-Substituted Carbazic Acids." Croatica Chemica Acta 52, br. 3 (1979): 293-298. https://hrcak.srce.hr/195889
Harvard
Srivastava, A.K. (1979). 'Metal Complexes of Carbazic Acids IV. Chromium(III) Complexes of N-Substituted Carbazic Acids', Croatica Chemica Acta, 52(3), str. 293-298. Preuzeto s: https://hrcak.srce.hr/195889 (Datum pristupa: 05.03.2021.)
Vancouver
Srivastava AK. Metal Complexes of Carbazic Acids IV. Chromium(III) Complexes of N-Substituted Carbazic Acids. Croatica Chemica Acta [Internet]. 1979 [pristupljeno 05.03.2021.];52(3):293-298. Dostupno na: https://hrcak.srce.hr/195889
IEEE
A.K. Srivastava, "Metal Complexes of Carbazic Acids IV. Chromium(III) Complexes of N-Substituted Carbazic Acids", Croatica Chemica Acta, vol.52, br. 3, str. 293-298, 1979. [Online]. Dostupno na: https://hrcak.srce.hr/195889. [Citirano: 05.03.2021.]

Sažetak
A series of N-substituted carbazic acid complexes of chromium(
III) with a general composition CrL3 (where L = carbazic
acid anion, methylcarbazate, phenylcarbazate, 2,3-dimethylcarbazate
and 3,3-dimethylcarbazate) was prepared. On the basis of
infrared and electronic spectroscopy and magnetism, the structure
of these complexes was identified. The ligand field parameters
were calculated from the spectral data; the values of IODq for the
complexes studied are essentially constant, varying only from
17.09 to 18.34 kK*. The values of B in the complexes were reduced
very significantly from the free-ion value for chromium(III). The
bonding occurs through one of the oxygen atoms of the carboxylate
group and amino nitrogen atom.

Hrčak ID: 195889

URI
https://hrcak.srce.hr/195889

Posjeta: 103 *