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Ferrocene Compounds. VIII. The Stobbe Condensations of Acylferrocenes with Diethyl Succinate

M. Laćan ; Laboratory of Applied Organic Chemistry, Biochemistry Department, Faculty of Technology, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia
V. Rapić ; Laboratory of Applied Organic Chemistry, Biochemistry Department, Faculty of Technology, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia

Sažetak

The Stobbe condensations of formyl-, acetyl-, and benzoylferrocene,
resp., with diethyl succinate gave mixtures of (E)- and
(Z)-stereoisomeric products, FcCR=C(C02Et)CH2C02H (R=H, Me,
and Ph, resp.). These mixtures have been separated into pure compounds
by chromatographic methods, and their structures have been
assigned by spectroscopic means.

Ključne riječi

Hrčak ID:

195937

URI

https://hrcak.srce.hr/195937

Datum izdavanja:

8.2.1979.

Posjeta: 373 *