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Izvorni znanstveni članak
Synthesis of Isomeric Hexahydro- and Perhydroisoindol-1-ones
V. Škarić
; Laboratory of Stereochemistry and Natural Products, »Ruder Bo!ikovic« Institute, 41001 Zagreb, Croatia, Yugoslavia
D. Frgačić
; Laboratory of Stereochemistry and Natural Products, »Ruder Bo!ikovic« Institute, 41001 Zagreb, Croatia, Yugoslavia
V. Turjak-Zebić
; Laboratory of Stereochemistry and Natural Products, »Ruder Bo!ikovic« Institute, 41001 Zagreb, Croatia, Yugoslavia
| Puni tekst: engleski, pdf (5 MB) | str. 97-106 | citiraj | |
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APA 6th Edition Škarić, V., Frgačić, D. i Turjak-Zebić, V. (1978). Synthesis of Isomeric Hexahydro- and Perhydroisoindol-1-ones. Croatica Chemica Acta, 51 (1), 97-106. Preuzeto s https://hrcak.srce.hr/195985 MLA 8th Edition Škarić, V., et al. "Synthesis of Isomeric Hexahydro- and Perhydroisoindol-1-ones." Croatica Chemica Acta, vol. 51, br. 1, 1978, str. 97-106. https://hrcak.srce.hr/195985. Citirano 20.09.2020. Chicago 17th Edition Škarić, V., D. Frgačić i V. Turjak-Zebić. "Synthesis of Isomeric Hexahydro- and Perhydroisoindol-1-ones." Croatica Chemica Acta 51, br. 1 (1978): 97-106. https://hrcak.srce.hr/195985 Harvard Škarić, V., Frgačić, D., i Turjak-Zebić, V. (1978). 'Synthesis of Isomeric Hexahydro- and Perhydroisoindol-1-ones', Croatica Chemica Acta, 51(1), str. 97-106. Preuzeto s: https://hrcak.srce.hr/195985 (Datum pristupa: 20.09.2020.) Vancouver Škarić V, Frgačić D, Turjak-Zebić V. Synthesis of Isomeric Hexahydro- and Perhydroisoindol-1-ones. Croatica Chemica Acta [Internet]. 1978 [pristupljeno 20.09.2020.];51(1):97-106. Dostupno na: https://hrcak.srce.hr/195985 IEEE V. Škarić, D. Frgačić i V. Turjak-Zebić, "Synthesis of Isomeric Hexahydro- and Perhydroisoindol-1-ones", Croatica Chemica Acta, vol.51, br. 1, str. 97-106, 1978. [Online]. Dostupno na: https://hrcak.srce.hr/195985. [Citirano: 20.09.2020.] |
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Sažetak
Catalytic hydrogenation of triethyl 2-cyanocyclohex-1-(XIV)
and -2(XV)-ene-1,5,5-tricarboxylates yielded the corresponding 2-
-cyanocyclohexane (XVII) and diethyl perhydroisoindol-1-one-6,6-
-dicarboxylate (V), the latter being formed through spontaneous
intramolecular cyclisation of triethyl 2-aminomethylcyclohexane-
1,5,5-tricarboxylate (XXI). Regiospecific reductions and isomerisations
of cyanocyclohexenes (XIV) and (XV), and their conversion
into corresponding hexahydroisoindol-1-ones (IV) and (III) were
shown to depend on the hydrogenating conditions and catalysts.
Hrčak ID: 195985
URI
https://hrcak.srce.hr/195985
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