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A Study of the Interactions Between the Double Bonds in Unsaturated Ketones

Nicolae Bodor ; Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712, U.S.A.
M. J. S. Dewar ; Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712, U.S.A.
Zvonimir B. Maksić ; Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712, U.S.A.

Sažetak

The interactions between C=C and C=O double bonds in
several unsaturated ketones have been studied by comparing
MIND0/2 caloulations wiith ionisation potentials determined by
photoelectron spectroscopy (PES). With one exception (norbornadienone)
the direct through-space interactions in conjugated .ketones
appear to be negligible, the double bonds couple hyperoonjugatively
via the intervening a bonds. This kind of approach should prove
useful for studying other long range interactions.

Ključne riječi

Hrčak ID:

196483

URI

https://hrcak.srce.hr/196483

Datum izdavanja:

20.2.1976.

Posjeta: 425 *