Croatica Chemica Acta, Vol. 46 No. 2, 1974.
Izvorni znanstveni članak
Ferrocene Compounds. V. Indirect Electrochemical Reduction of Acetylferrocene
M. Laćan
; Faculty of Technology, University of Zagreb
Z. Ibrišagić
; Institute of Food Science and Technology, 41000 Zagreb, Croatia, Yugoslavia
Sažetak
2,3-Diferrocenyl-2,3-butanediol (II) has been obtained by the
indirect electrochemical reduction of acetylferrocerie (I) using an
electrochemically generated sodium amalgam. The approximative
value of the half-wave reduction potential of acetylferrocene (I) .
and the stereochemistry of (II) has been determined. Pinacol (II)
was rearranged to 2,3-diferrocenylbutane-3-on (III) , dehydrated
to 2,3-diferrocenyl-1,3-butadiene (IV) and anhydride of 4,5- diferrocenyl-
4-cyclohexene-1,2-dicarboxylic aC!id (V) was formed by the
Diels-Alder reaction of (IV).
Ključne riječi
Hrčak ID:
196825
URI
Datum izdavanja:
1.11.1974.
Posjeta: 760 *